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Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si
https://hiroshima.repo.nii.ac.jp/records/2008908
https://hiroshima.repo.nii.ac.jp/records/2008908ab9edb00-d100-4caf-bee4-8b3711688543
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
TheChemRec_16_419.pdf (2.0 MB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||
|---|---|---|---|---|---|---|---|---|
| 公開日 | 2023-03-18 | |||||||
| タイトル | ||||||||
| タイトル | Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si | |||||||
| 言語 | en | |||||||
| 作成者 |
Yoshida, Hiroto
× Yoshida, Hiroto
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| アクセス権 | ||||||||
| アクセス権 | open access | |||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||
| 権利情報 | ||||||||
| 権利情報 | © 2016 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | boron | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | copper | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | metalation | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | silicon | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | tin | |||||||
| 内容記述 | ||||||||
| 内容記述 | A copper complex has proven to be a potent catalyst for forming a C–B bond via diborylation of arynes and alkynes, affording vic-diborylarenes and vic-diborylalkenes with high efficiency. A boryl-substituted organocopper species, which is intermediately generated in the diborylation, has been found to be captured by a tin or a carbon electrophile, leading to threecomponent borylstannylation or carboboration, in which C–B and C–Sn (or C) bonds are constructed simultaneously. Furthermore, reducing the Lewis acidity of the boron center with 1,8-diaminonaphthalene decisively alters the regiochemical behavior of the borylcopper species, enabling the installation of a boryl moiety to occur at an internal carbon of terminal alkynes in borylstannylation and protoboration. Copper catalysis for C–Sn and C–Si bond-forming processes via distannylation, hydrostannylation and silylstannylation, as well as silver catalysis for a C–B bond-forming reaction, is also described. | |||||||
| 言語 | en | |||||||
| 内容記述 | ||||||||
| 内容記述タイプ | Other | |||||||
| 内容記述 | This work was financially supported by Research for Promoting Technological Seeds from the Japan Science and Technology Agency (JST), the Electric Technology Research Foundation of Chugoku, The Mazda Foundation, the Furukawa Technology Promotion Foundation, and the SEI Group CSR Foundation. | |||||||
| 出版者 | ||||||||
| 出版者 | Wiley | |||||||
| 言語 | ||||||||
| 言語 | eng | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
| 資源タイプ | journal article | |||||||
| 出版タイプ | ||||||||
| 出版タイプ | VoR | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
| 関連情報 | ||||||||
| 識別子タイプ | DOI | |||||||
| 関連識別子 | 10.1002/tcr.201500227 | |||||||
| 関連情報 | ||||||||
| 識別子タイプ | DOI | |||||||
| 関連識別子 | https://doi.org/10.1002/tcr.201500227 | |||||||
| 収録物識別子 | ||||||||
| 収録物識別子タイプ | ISSN | |||||||
| 収録物識別子 | 1527-8999 | |||||||
| 収録物識別子 | ||||||||
| 収録物識別子タイプ | ISSN | |||||||
| 収録物識別子 | 1528-0691 | |||||||
| 開始ページ | ||||||||
| 開始ページ | 419 | |||||||
| 書誌情報 |
The Chemical Record The Chemical Record 巻 16, 号 1, p. 419-434, 発行日 2016-01-20 |
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| 旧ID | 48767 | |||||||
