{"created":"2025-02-21T04:38:41.855134+00:00","id":2008908,"links":{},"metadata":{"_buckets":{"deposit":"3eb9ccda-0b57-4787-af7b-bacfd2c9afb5"},"_deposit":{"created_by":41,"id":"2008908","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2008908"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02008908","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yoshida, Hiroto","creatorNameLang":"en"}],"familyNames":[{"familyName":"Yoshida","familyNameLang":"en"}],"givenNames":[{"givenName":"Hiroto","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2016 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes."}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"boron","subitem_subject_scheme":"Other"},{"subitem_subject":"copper","subitem_subject_scheme":"Other"},{"subitem_subject":"metalation","subitem_subject_scheme":"Other"},{"subitem_subject":"silicon","subitem_subject_scheme":"Other"},{"subitem_subject":"tin","subitem_subject_scheme":"Other"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"A copper complex has proven to be a potent catalyst for forming a C–B bond via diborylation of arynes and alkynes, affording vic-diborylarenes and vic-diborylalkenes with high efficiency. A boryl-substituted organocopper species, which is intermediately generated in the diborylation, has been found to be captured by a tin or a carbon electrophile, leading to threecomponent borylstannylation or carboboration, in which C–B and C–Sn (or C) bonds are constructed simultaneously. Furthermore, reducing the Lewis acidity of the boron center with 1,8-diaminonaphthalene decisively alters the regiochemical behavior of the borylcopper species, enabling the installation of a boryl moiety to occur at an internal carbon of terminal alkynes in borylstannylation and protoboration. Copper catalysis for C–Sn and C–Si bond-forming processes via distannylation, hydrostannylation and silylstannylation, as well as silver catalysis for a C–B bond-forming reaction, is also described.","subitem_description_language":"en"},{"subitem_description":"This work was financially supported by Research for Promoting Technological Seeds from the Japan Science and Technology Agency (JST), the Electric Technology Research Foundation of Chugoku, The Mazda Foundation, the Furukawa Technology Promotion Foundation, and the SEI Group CSR Foundation.","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Wiley"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"1527-8999","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1528-0691","subitem_source_identifier_type":"ISSN"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"419"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-01-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"434","bibliographicPageStart":"419","bibliographicVolumeNumber":"16","bibliographic_titles":[{"bibliographic_title":"The Chemical Record"},{"bibliographic_title":"The Chemical Record"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/tcr.201500227","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/tcr.201500227","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"TheChemRec_16_419.pdf","filesize":[{"value":"2.0 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2008908/files/TheChemRec_16_419.pdf"},"version_id":"2d1d04d3-9b84-4cc5-87ea-8baec3be45ff"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"48767"},"item_title":"Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2008908","relation_version_is_last":true,"title":["Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-22T04:34:58.201577+00:00"}