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Highly conductive nano-sized Magnéli phases titanium oxide (TiOx)

https://hiroshima.repo.nii.ac.jp/records/2008796
https://hiroshima.repo.nii.ac.jp/records/2008796
4fc39810-36df-451a-a948-8902d0f86475
名前 / ファイル ライセンス アクション
SciRep_7_3646.pdf SciRep_7_3646.pdf (2.4 MB)
Item type デフォルトアイテムタイプ_(フル)(1)
公開日 2023-03-18
タイトル
タイトル Highly conductive nano-sized Magnéli phases titanium oxide (TiOx)
言語 en
作成者 Arif, Aditya F

× Arif, Aditya F

en Arif, Aditya F

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Balgis, Ratna

× Balgis, Ratna

en Balgis, Ratna

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Ogi, Takasi

× Ogi, Takasi

en Ogi, Takasi

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Iskandar, Ferry

× Iskandar, Ferry

en Iskandar, Ferry

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Kinoshita, Akihiro

× Kinoshita, Akihiro

en Kinoshita, Akihiro

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Nakamura, Keitaro

× Nakamura, Keitaro

en Nakamura, Keitaro

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Okuyama, Kikuo

× Okuyama, Kikuo

en Okuyama, Kikuo

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アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利情報
権利情報 © The Author(s) 2017. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
内容記述
内容記述 Despite the strong recent revival of Magnéli phase TiOx as a promising conductive material, synthesis of Magnéli phase TiOx nanoparticles has been a challenge because of the heavy sintering nature of TiO2 at elevated temperatures. We have successfully synthesized chain-structured Magnéli phases TiOx with diameters under 30 nm using a thermal-induced plasma process. The synthesized nanoparticles consisted of a mixture of several Magnéli phases. A post-synthesis heat-treatment was performed to reduce the electrical resistivity without changing the particle morphology. The resistivity of the heat-treated particle was as low as 0.04 Ω.cm, with a specific surface area of 52.9 m2 g−1. The effects of heat-treatment on changes in the crystal structure and their correlation with the electron conductivity are discussed based on transmission electron microscopy images, X-ray diffraction spectra, and X-ray adsorption fine structure spectra. Electrochemical characterization using cyclic voltammetry and potentiodynamic scan shows a remarkable electrochemical stability in a strongly oxidizing environment.
言語 en
内容記述
内容記述タイプ Other
内容記述 This work was partially supported by a Hosokawa Grant for Promising Researchers from Hosokawa Powder Technology Foundation, JSPS KAKENHI Grant Numbers 2670906, Grant-in-Aid for Young Scientists B (15K182570A), and Center for Functional Nano Oxide at Hiroshima University.
出版者
出版者 Nature Research
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
関連情報
識別子タイプ DOI
関連識別子 10.1038/s41598-017-03509-y
関連情報
識別子タイプ PMID
関連識別子 28623278
関連情報
識別子タイプ DOI
関連識別子 https://doi.org/10.1038/s41598-017-03509-y
収録物識別子
収録物識別子タイプ ISSN
収録物識別子 2045-2322
開始ページ
開始ページ 3646
書誌情報 Scientific Reports
Scientific Reports

巻 7, p. 3646, 発行日 2017-06-16
旧ID 48727
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