{"created":"2025-02-21T04:35:14.524317+00:00","id":2008796,"links":{},"metadata":{"_buckets":{"deposit":"f6549d39-7242-4cf9-97ae-481b8223eb43"},"_deposit":{"created_by":41,"id":"2008796","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2008796"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02008796","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Highly conductive nano-sized Magnéli phases titanium oxide (TiOx)","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Arif, Aditya F","creatorNameLang":"en"}],"familyNames":[{"familyName":"Arif","familyNameLang":"en"}],"givenNames":[{"givenName":"Aditya F","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Balgis, Ratna","creatorNameLang":"en"}],"familyNames":[{"familyName":"Balgis","familyNameLang":"en"}],"givenNames":[{"givenName":"Ratna","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ogi, Takasi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ogi","familyNameLang":"en"}],"givenNames":[{"givenName":"Takasi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Iskandar, Ferry","creatorNameLang":"en"}],"familyNames":[{"familyName":"Iskandar","familyNameLang":"en"}],"givenNames":[{"givenName":"Ferry","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kinoshita, Akihiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Kinoshita","familyNameLang":"en"}],"givenNames":[{"givenName":"Akihiro","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nakamura, Keitaro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Nakamura","familyNameLang":"en"}],"givenNames":[{"givenName":"Keitaro","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Okuyama, Kikuo","creatorNameLang":"en"}],"familyNames":[{"familyName":"Okuyama","familyNameLang":"en"}],"givenNames":[{"givenName":"Kikuo","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© The Author(s) 2017. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/."}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Despite the strong recent revival of Magnéli phase TiOx as a promising conductive material, synthesis of Magnéli phase TiOx nanoparticles has been a challenge because of the heavy sintering nature of TiO2 at elevated temperatures. We have successfully synthesized chain-structured Magnéli phases TiOx with diameters under 30 nm using a thermal-induced plasma process. The synthesized nanoparticles consisted of a mixture of several Magnéli phases. A post-synthesis heat-treatment was performed to reduce the electrical resistivity without changing the particle morphology. The resistivity of the heat-treated particle was as low as 0.04 Ω.cm, with a specific surface area of 52.9 m2 g−1. The effects of heat-treatment on changes in the crystal structure and their correlation with the electron conductivity are discussed based on transmission electron microscopy images, X-ray diffraction spectra, and X-ray adsorption fine structure spectra. Electrochemical characterization using cyclic voltammetry and potentiodynamic scan shows a remarkable electrochemical stability in a strongly oxidizing environment.","subitem_description_language":"en"},{"subitem_description":"This work was partially supported by a Hosokawa Grant for Promising Researchers from Hosokawa Powder Technology Foundation, JSPS KAKENHI Grant Numbers 2670906, Grant-in-Aid for Young Scientists B (15K182570A), and Center for Functional Nano Oxide at Hiroshima University. ","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Nature Research"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"2045-2322","subitem_source_identifier_type":"ISSN"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"3646"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-06-16","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"3646","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"Scientific Reports"},{"bibliographic_title":"Scientific Reports"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1038/s41598-017-03509-y","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"28623278","subitem_relation_type_select":"PMID"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1038/s41598-017-03509-y","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"SciRep_7_3646.pdf","filesize":[{"value":"2.4 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2008796/files/SciRep_7_3646.pdf"},"version_id":"5f0add39-96e3-43bd-8a69-4d02325e9684"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"48727"},"item_title":"Highly conductive nano-sized Magnéli phases titanium oxide (TiOx)","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2008796","relation_version_is_last":true,"title":["Highly conductive nano-sized Magnéli phases titanium oxide (TiOx)"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-22T04:21:54.236184+00:00"}