Item type |
デフォルトアイテムタイプ_(フル)(1) |
公開日 |
2025-01-10 |
タイトル |
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タイトル |
Synthesis and characterization of alginate-polyacrylic acid/multiwalled carbon nanotubes composite with efficient removal for nigrosine dye |
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言語 |
en |
作成者 |
Ibrahim, Mohamed
Abdelmonem, Islam M.
Mohamed, Laila A.
Gizawy, Mohamed A.
Metwally, E.
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アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
権利情報 |
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言語 |
en |
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権利情報 |
This is an Accepted Manuscript of an article published by Taylor & Francis in Polymer-Plastics Technology and Materials on 29 Mar 2024, available at: https://doi.org/10.1080/25740881.2024.2328614. |
権利情報 |
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言語 |
en |
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権利情報 |
This is not the published version. Please cite only the published version. |
権利情報 |
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言語 |
ja |
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権利情報 |
この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。 |
主題 |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
Alginate-polyacrylic acid/multiwalled carbon nanotubes |
主題 |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
biosorption |
主題 |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
kinetics |
主題 |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
nigrosine |
主題 |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
thermodynamics |
内容記述 |
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内容記述 |
The current study detailed the efficacy of a simply prepared alginate-polyacrylic acid/functionalized multiwalled carbon nanotubes (Alg-PAA/f-MWCNTs) composite for adsorption of nigrosine dye (acid black II) from aqueous environments. Firstly, preparation of the Alg-PAA/f-MWCNTs composite was achieved via gamma radiation-induced template polymerization of AA onto the Alg/f-MWCNTs surface. The maximum grafting efficiency (GE%) of AA onto the surface of Alg/f-MWCNTs was ~ 82% under the optimized conditions: (2.5 wt% Alg, 30 wt% AA, 0.5 wt% f-MWCNTs, 0.6 wt% N,N’-methylenebisacrylamide (NMBA), and irradiation dose ~ 20 kGy). The structural characteristics, thermal features as well as the morphological appearance of the Alg-PAA/f-MWCNTs composite were validated using different analyses including FTIR, TGA, DTA, XRD and SEM. Additionally, the composite exhibited uniform particle size distribution (~150.7 nm), point of zero charge at pH = 6.28, and negative Zeta potentials of a minimum at pH = 2. The adsorption batch experiments showed good adsorption capacity for the nigrosine dye from their aqueous media with adsorption efficiency up to 83% using the batch technique at pH = 2.0 for 420 min. The adsorption of nigrosine dye onto Alg-PAA/f-MWCNTs is favorable thermodynamically, obeying the Freundlich isotherm model and controlled by a chemisorption mechanism. Additionally, the composite showed a good regeneration ability up to five times with almost the same removal of ~80%. The results demonstrated that the Alg-PAA/f-MWCNTs composite could be a promising candidate for the removal of nigrosine dye from industrial aqueous environments. |
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言語 |
en |
出版者 |
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出版者 |
Taylor & Francis |
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言語 |
en |
言語 |
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言語 |
eng |
資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
関連情報 |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1080/25740881.2024.2328614 |
開始ページ |
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開始ページ |
1277 |
書誌情報 |
en : Polymer-Plastics Technology and Materials
巻 63,
号 10,
p. 1277-1293,
発行日 2024-03-29
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旧ID |
56102 |