| Item type |
デフォルトアイテムタイプ_（フル）(1) |
| 公開日 |
2023-03-18 |
| タイトル |
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タイトル |
Infrared photodissociation spectroscopy of [Al(NH3)n]+ (n = 1-5) : solvation structures and insertion reactions of Al+ into NH3 |
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言語 |
en |
| 作成者 |
Mune, Yutaka
Ohashi, Kazuhiko
Iino, Takuro
Inokuchi, Yoshiya
Judai, Ken
Nishi, Nobuyuki
Sekiya, Hiroshi
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| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
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権利情報 |
(c) 2005 Published by Elsevier B.V. |
| 主題 |
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主題Scheme |
NDC |
|
主題 |
430 |
| 内容記述 |
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内容記述 |
The [Al(NH3)n]+ ions with n = 1–5 are studied by infrared photodissociation spectroscopy and density functional theory calculations. The inserted [H–Al–NH2]+ structure is calculated to be higher in energy than the adduct [Al–NH3]+ structure. However, incremental solvation stabilizes the inserted structure more efficiently than the adduct structure, because of a larger effective charge on the Al atom in [H–Al–NH2]+. Actually, the infrared spectra demonstrate that the [(H–Al–NH2)(NH3)n–1]+ ions are predominant over [Al–(NH3)n]+ for n ≥ 4, while the adduct structures dominate the spectra of [Al(NH3)n・Ar]+ for n = 1–3. |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Other |
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内容記述 |
This work was supported in part by the Joint Studies Program (2004) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (No. 17550014) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. |
| 内容記述 |
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内容記述タイプ |
Other |
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内容記述 |
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2006, available online: http://doi.org/10.1016/j.cplett.2005.11.077 |
| 出版者 |
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出版者 |
Elsevier B.V. |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 出版タイプ |
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出版タイプ |
AO |
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出版タイプResource |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| 関連情報 |
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識別子タイプ |
DOI |
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関連識別子 |
10.1016/j.cplett.2005.11.077 |
| 関連情報 |
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関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
http://doi.org/10.1016/j.cplett.2005.11.077 |
| 収録物識別子 |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
0009-2614 |
| 開始ページ |
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開始ページ |
201 |
| 書誌情報 |
Chemical Physics Letters
Chemical Physics Letters
巻 419,
号 1–3,
p. 201-206,
発行日 2006-02-15
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| 旧ID |
38232 |
ChemPhysLett_2006_419_201.pdf (707.4 KB)
