{"created":"2025-02-21T03:26:48.316430+00:00","id":2006618,"links":{},"metadata":{"_buckets":{"deposit":"da770f57-93f7-4de1-a468-b42bfc05da0f"},"_deposit":{"created_by":41,"id":"2006618","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2006618"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02006618","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Infrared photodissociation spectroscopy of [Al(NH3)n]+ (n = 1-5) : solvation structures and insertion reactions of Al+ into NH3","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Mune, Yutaka","creatorNameLang":"en"}],"familyNames":[{"familyName":"Mune","familyNameLang":"en"}],"givenNames":[{"givenName":"Yutaka","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ohashi, Kazuhiko","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ohashi","familyNameLang":"en"}],"givenNames":[{"givenName":"Kazuhiko","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Iino, Takuro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Iino","familyNameLang":"en"}],"givenNames":[{"givenName":"Takuro","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Inokuchi, Yoshiya","creatorNameLang":"en"}],"familyNames":[{"familyName":"Inokuchi","familyNameLang":"en"}],"givenNames":[{"givenName":"Yoshiya","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Judai, Ken","creatorNameLang":"en"}],"familyNames":[{"familyName":"Judai","familyNameLang":"en"}],"givenNames":[{"givenName":"Ken","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nishi, Nobuyuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Nishi","familyNameLang":"en"}],"givenNames":[{"givenName":"Nobuyuki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Sekiya, Hiroshi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Sekiya","familyNameLang":"en"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"(c) 2005 Published by Elsevier B.V."}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"The [Al(NH3)n]+ ions with n = 1–5 are studied by infrared photodissociation spectroscopy and density functional theory calculations. The inserted [H–Al–NH2]+ structure is calculated to be higher in energy than the adduct [Al–NH3]+ structure. However, incremental solvation stabilizes the inserted structure more efficiently than the adduct structure, because of a larger effective charge on the Al atom in [H–Al–NH2]+. Actually, the infrared spectra demonstrate that the [(H–Al–NH2)(NH3)n–1]+ ions are predominant over [Al–(NH3)n]+ for n ≥ 4, while the adduct structures dominate the spectra of [Al(NH3)n・Ar]+ for n = 1–3.","subitem_description_language":"en"},{"subitem_description":"This work was supported in part by the Joint Studies Program (2004) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (No. 17550014) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan.","subitem_description_type":"Other"},{"subitem_description":"This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2006, available online: http://doi.org/10.1016/j.cplett.2005.11.077","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Elsevier B.V."}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"0009-2614","subitem_source_identifier_type":"ISSN"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"201"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-02-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1–3","bibliographicPageEnd":"206","bibliographicPageStart":"201","bibliographicVolumeNumber":"419","bibliographic_titles":[{"bibliographic_title":"Chemical Physics Letters "},{"bibliographic_title":"Chemical Physics Letters "}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.cplett.2005.11.077","subitem_relation_type_select":"DOI"}},{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.1016/j.cplett.2005.11.077","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"ChemPhysLett_2006_419_201.pdf","filesize":[{"value":"707.4 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2006618/files/ChemPhysLett_2006_419_201.pdf"},"version_id":"52082105-5bbc-4941-8bfb-c53f8b8a7e7a"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"38232"},"item_title":"Infrared photodissociation spectroscopy of [Al(NH3)n]+ (n = 1-5) : solvation structures and insertion reactions of Al+ into NH3","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2006618","relation_version_is_last":true,"title":["Infrared photodissociation spectroscopy of [Al(NH3)n]+ (n = 1-5) : solvation structures and insertion reactions of Al+ into NH3"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T07:58:45.606201+00:00"}