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Pore size tuning of bis(triethoxysilyl)propane (BTESP)-derived membrane for gas separation: Effects of the acid molar ratio in the sol and of the calcination temperature
https://hiroshima.repo.nii.ac.jp/records/2008827
https://hiroshima.repo.nii.ac.jp/records/2008827aacf638c-118e-4436-a6c0-6cf4ef44451e
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SeparPurifTech_242_116742.pdf (645.6 KB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2023-03-18 | |||||||||||||||||
| タイトル | ||||||||||||||||||
| タイトル | Pore size tuning of bis(triethoxysilyl)propane (BTESP)-derived membrane for gas separation: Effects of the acid molar ratio in the sol and of the calcination temperature | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 作成者 |
Inoue, Ryota
× Inoue, Ryota
× Kanezashi, Masakoto
× Nagasawa, Hiroki
× Yamamoto, Kazuki
× Gunji, Takahiro
× Tsuru, Toshinori
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| アクセス権 | ||||||||||||||||||
| アクセス権 | open access | |||||||||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||||||
| 権利情報 | ||||||||||||||||||
| 権利情報 | © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||||||||||||||
| 権利情報 | ||||||||||||||||||
| 権利情報 | This is not the published version. Please cite only the published version. この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。 | |||||||||||||||||
| 主題 | ||||||||||||||||||
| 主題Scheme | Other | |||||||||||||||||
| 主題 | Organosilica | |||||||||||||||||
| 主題 | ||||||||||||||||||
| 主題Scheme | Other | |||||||||||||||||
| 主題 | Membrane | |||||||||||||||||
| 主題 | ||||||||||||||||||
| 主題Scheme | Other | |||||||||||||||||
| 主題 | Gas separation | |||||||||||||||||
| 主題 | ||||||||||||||||||
| 主題Scheme | Other | |||||||||||||||||
| 主題 | Pore size | |||||||||||||||||
| 主題 | ||||||||||||||||||
| 主題Scheme | Other | |||||||||||||||||
| 主題 | Activation energy | |||||||||||||||||
| 内容記述 | ||||||||||||||||||
| 内容記述 | Bis(triethoxysilyl)propane (BTESP) is a bridged-type organoalkoxysilane with a Si-C3H6-Si bond. It was utilized for membrane fabrication via a sol-gel method to achieve high permselectivity for large molecules. Membrane fabrication parameters such as the acid molar ratio (AR) in the sol and calcination temperature were evaluated for their effect on the network pore size and on gas permeation properties, as evaluated by the molecular size dependence (0.26–0.55 nm) and temperature dependence (50–200 °C) of gas permeance. BTESP membranes with different ARs (10−1, 100, and 10) showed H2/N2 and H2/CF4 selectivities of 20–30 and 640–32,000, respectively. As AR was increased, each gas permeance also increased, but H2 selectivity that corresponds to network pore size was decreased. FT-IR analysis indicated that the density of the Si-OH groups (Si-OH/Si-O-Si) of unfired gels was decreased with a higher AR, so that condensation of the Si-OH groups during the calcination process formed a dense network structure in the case of BTESP membranes with a low AR (10−1). Calcination temperature also affected the network structure of BTESP membranes. BTESP membranes calcined at different temperatures (350, 450, and 600 °C) showed H2/N2 and H2/CF4 selectivities of 10–30 and 410–32,000, respectively. A BTESP membrane calcined at high temperature (600 °C) showed loose networks since the linking units derived from BTESP were decomposed at temperatures above 500 °C, which resulted in the formation of methyl groups. In conclusion, the AR in a sol is suitable for tuning small pore sizes, while calcination temperature as a membrane fabrication parameter offers the advantage of controllability for loose network structures. | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 出版者 | ||||||||||||||||||
| 出版者 | Elsevier | |||||||||||||||||
| 言語 | ||||||||||||||||||
| 言語 | eng | |||||||||||||||||
| 資源タイプ | ||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||
| 出版タイプ | ||||||||||||||||||
| 出版タイプ | AO | |||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_b1a7d7d4d402bcce | |||||||||||||||||
| 関連情報 | ||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||
| 関連識別子 | 10.1016/j.seppur.2020.116742 | |||||||||||||||||
| 関連情報 | ||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||
| 関連識別子 | https://doi.org/10.1016/j.seppur.2020.116742 | |||||||||||||||||
| 収録物識別子 | ||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||
| 収録物識別子 | 1383-5866 | |||||||||||||||||
| 開始ページ | ||||||||||||||||||
| 開始ページ | 116742 | |||||||||||||||||
| 書誌情報 |
Separation and Purification Technology Separation and Purification Technology 巻 242, p. 116742, 発行日 2020-07-01 |
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| 旧ID | 50508 | |||||||||||||||||
| 備考 | The full-text file will be made open to the public on 1 July 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving' | |||||||||||||||||
