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Orbital-ordering-induced phase transition in LaVO3 and CeVO3

https://hiroshima.repo.nii.ac.jp/records/2008219
https://hiroshima.repo.nii.ac.jp/records/2008219
60653c5b-2e3f-4820-9ecf-61017d1c0e20
名前 / ファイル ライセンス アクション
PhysRevB_67_014107.pdf PhysRevB_67_014107.pdf (523.7 KB)
Item type デフォルトアイテムタイプ_(フル)(1)
公開日 2023-03-18
タイトル
タイトル Orbital-ordering-induced phase transition in LaVO3 and CeVO3
言語 en
作成者 Ren, Y.

× Ren, Y.

en Ren, Y.

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Nugroho, Agung A.

× Nugroho, Agung A.

en Nugroho, Agung A.

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Menovsky, Alois A.

× Menovsky, Alois A.

en Menovsky, Alois A.

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Strempfer, J.

× Strempfer, J.

en Strempfer, J.

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Rütt, U.

× Rütt, U.

en Rütt, U.

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Iga, Fumitoshi

× Iga, Fumitoshi

en Iga, Fumitoshi

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Takabatake, Toshiro

× Takabatake, Toshiro

en Takabatake, Toshiro

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Kimball, Clyde W.

× Kimball, Clyde W.

en Kimball, Clyde W.

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アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利情報
権利情報 Copyright (c) 2003 American Physical Society.
内容記述
内容記述 The structural phase transition in the orthovanadates LaVO3 and CeVO3 has been studied with high energy synchrotron x-ray diffraction. LaVO3 undergoes a second order phase transition at TN = 143 K and a first order transition at Tt = 141 K, while in CeVO3 there are phase transitions occurring at T0 = 154 K of second order and at TN = 134 K of first order. These phase transitions are confirmed by specific heat measurements. The phase transition at Tt in LaVO3 or T0 in CeVO3 is due to a G-type orbital ordering which lowers the structure symmetry from orthorhombic Pbnm to monoclinic P2t/b11. The structure change at TN in CeVO3 is ascribed to an orbital ordering enhanced magnetostrictive distortion, while that at TN in LaVO3 is most probably due to an ordered occupation of the vanadium 3d t2g orbitals associated with an antiferromagnetic ordering. We propose that the first order phase transition at Tt in LaVO3 should be associated with a sudden change of both spin and orbital configurations, similar to the phase transition at Ts = 77 K in YVO3 [Ren et al., Nature (London) 396, 441 (1998)], causing a reversal of the net magnetization. However, the ordered state above Tt in LaVO3 is identical to that below Ts in YVO3. It is found that, with increasing lanthanide ionic radius, the Néel temperature TN increases while the orbital ordering onset temperature decreases in these orthovanadates.
言語 en
出版者
出版者 American Physical Society
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
関連情報
識別子タイプ DOI
関連識別子 10.1103/PhysRevB.67.014107
関連情報
識別子タイプ DOI
関連識別子 http://dx.doi.org/10.1103/PhysRevB.67.014107
収録物識別子
収録物識別子タイプ ISSN
収録物識別子 0163-1829
収録物識別子
収録物識別子タイプ NCID
収録物識別子 AA11187113
開始ページ
開始ページ 014107-1
書誌情報 Physical Review B - Condensed Matter and Materials Physics
Physical Review B - Condensed Matter and Materials Physics

巻 67, 号 1, p. 014107-1-014107-6, 発行日 2003-01-24
旧ID 18723
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