| Item type |
デフォルトアイテムタイプ_（フル）(1) |
| 公開日 |
2025-01-17 |
| タイトル |
|
|
タイトル |
Synthesis of liquid crystalline compounds containing thiol groups at both ends as reactive substituents and their immobilization on a gold substrate |
|
言語 |
en |
| 作成者 |
Imae, Ichiro
Tsukiyama, Kazuki
Harima, Yutaka
|
| アクセス権 |
|
|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
|
|
言語 |
en |
|
権利情報 |
This is an Accepted Manuscript of an article published by Taylor & Francis in Molecular Crystals and Liquid Crystals on 30 May 2024, available at: https://doi.org/10.1080/15421406.2024.2353972. |
| 権利情報 |
|
|
言語 |
en |
|
権利情報 |
This is not the published version. Please cite only the published version. |
| 権利情報 |
|
|
言語 |
ja |
|
権利情報 |
この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。 |
| 主題 |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
gold electrode |
| 主題 |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
liquid crystalline compounds |
| 主題 |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
molecular orientation |
| 主題 |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
thiol group |
| 内容記述 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
In this study, we synthesized four bifunctional compounds containing two alkoxy groups, at which reactive thiol groups were introduced. Among these compounds, a compound with four and five methylene units in each alkyl chain did not exhibit a liquid crystalline phase. The other three compounds exhibit one or two liquid crystalline phases, and the number of liquid crystalline phases depends on the number of methylene units in their alkyl chains. These liquid crystalline compounds were oriented in one direction using a rubbed alignment film, and the oriented compounds were transferred onto a gold substrate. Using these gold substrates as working electrodes, cyclic voltammetry (CV) was performed with potassium ferricyanide as the redox probe. As the deposition time increased, the current intensities of a pair of redox waves gradually decreased. This trend suggests that with longer deposition times, a larger amount of the liquid crystalline compound was transferred to the gold substrate surface. These findings shed light on the relationship among the structures of bifunctional compounds, their liquid crystalline behavior, and their alignment properties on gold substrates, thereby offering valuable insights for potential applications in nanotechnology and materials science. |
|
言語 |
en |
| 出版者 |
|
|
出版者 |
Taylor & Francis |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
https://doi.org/10.1080/15421406.2024.2353972 |
| 開始ページ |
|
|
開始ページ |
520 |
| 書誌情報 |
en : Molecular Crystals and Liquid Crystals
巻 768,
号 12,
p. 520-531,
発行日 2024-05-30
|
MCLC_768_520.pdf (775.2 KB)
