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Synthesis of liquid crystalline compounds containing thiol groups at both ends as reactive substituents and their immobilization on a gold substrate

https://hiroshima.repo.nii.ac.jp/records/2007727
https://hiroshima.repo.nii.ac.jp/records/2007727
7d43b78a-9448-4e43-9769-14aa720eeefd
名前 / ファイル ライセンス アクション
MCLC_768_520.pdf MCLC_768_520.pdf (775.2 KB)
Item type デフォルトアイテムタイプ_(フル)(1)
公開日 2025-01-17
タイトル
タイトル Synthesis of liquid crystalline compounds containing thiol groups at both ends as reactive substituents and their immobilization on a gold substrate
言語 en
作成者 Imae, Ichiro

× Imae, Ichiro

en Imae, Ichiro

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Tsukiyama, Kazuki

× Tsukiyama, Kazuki

en Tsukiyama, Kazuki

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Harima, Yutaka

× Harima, Yutaka

en Harima, Yutaka

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アクセス権
アクセス権 embargoed access
アクセス権URI http://purl.org/coar/access_right/c_f1cf
権利情報
言語 en
権利情報 This is an Accepted Manuscript of an article published by Taylor & Francis in Molecular Crystals and Liquid Crystals on 30 May 2024, available at: https://doi.org/10.1080/15421406.2024.2353972.
権利情報
言語 en
権利情報 This is not the published version. Please cite only the published version.
権利情報
言語 ja
権利情報 この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。
主題
言語 en
主題Scheme Other
主題 gold electrode
主題
言語 en
主題Scheme Other
主題 liquid crystalline compounds
主題
言語 en
主題Scheme Other
主題 molecular orientation
主題
言語 en
主題Scheme Other
主題 thiol group
内容記述
内容記述 In this study, we synthesized four bifunctional compounds containing two alkoxy groups, at which reactive thiol groups were introduced. Among these compounds, a compound with four and five methylene units in each alkyl chain did not exhibit a liquid crystalline phase. The other three compounds exhibit one or two liquid crystalline phases, and the number of liquid crystalline phases depends on the number of methylene units in their alkyl chains. These liquid crystalline compounds were oriented in one direction using a rubbed alignment film, and the oriented compounds were transferred onto a gold substrate. Using these gold substrates as working electrodes, cyclic voltammetry (CV) was performed with potassium ferricyanide as the redox probe. As the deposition time increased, the current intensities of a pair of redox waves gradually decreased. This trend suggests that with longer deposition times, a larger amount of the liquid crystalline compound was transferred to the gold substrate surface. These findings shed light on the relationship among the structures of bifunctional compounds, their liquid crystalline behavior, and their alignment properties on gold substrates, thereby offering valuable insights for potential applications in nanotechnology and materials science.
言語 en
出版者
出版者 Taylor & Francis
言語 en
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1080/15421406.2024.2353972
開始ページ
開始ページ 520
書誌情報 en : Molecular Crystals and Liquid Crystals

巻 768, 号 12, p. 520-531, 発行日 2024-05-30
旧ID 56123
備考 The full-text file will be made open to the public on 30 May 2025 in accordance with publisher's 'Terms and Conditions for Self-Archiving'
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