| Item type |
デフォルトアイテムタイプ_（フル）(1) |
| 公開日 |
2023-03-18 |
| タイトル |
|
|
タイトル |
Mesoporous Microspheres of Nickel-based Layered Hydroxides by Aerosol-Assisted Self-Assembly using Crystalline Nano-Building Blocks. |
|
言語 |
en |
| 作成者 |
Tarutani, Naoki
Tokudome, Yasuaki
Jobbágy, Matías
Soler-Illia, Galo J. A. A.
Takahashi, Masahide
|
| アクセス権 |
|
|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
|
|
権利情報 |
© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2018 |
| 権利情報 |
|
|
権利情報 |
This version of the article has been accepted for publication, after peer review (when applicable) and is subject to Springer Nature’s AM terms of use, but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: https://doi.org/10.1007/s10971-018-4810-z |
| 権利情報 |
|
|
権利情報 |
This is not the published version. Please cite only the published version. この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。 |
| 主題 |
|
|
主題Scheme |
Other |
|
主題 |
Crystalline mesoporous microspheres |
| 主題 |
|
|
主題Scheme |
Other |
|
主題 |
nano-building blocks |
| 主題 |
|
|
主題Scheme |
Other |
|
主題 |
layered nickel hydroxides |
| 主題 |
|
|
主題Scheme |
Other |
|
主題 |
layered double hydroxides |
| 主題 |
|
|
主題Scheme |
Other |
|
主題 |
epoxide-mediated alkalinization |
| 内容記述 |
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|
内容記述 |
Structural control in micro- and nanometer scale is necessary to design highly functional materials. Crystalline mesoporous microspheres are expected to improve electrochemical, catalytic, and adsorption performances. In this study, we focused on the preparation of templated mesoporous microspheres of nickel-based layered hydroxides by using pre-crystallized nano-building blocks (NBBs). Layered nickel hydroxide nanoparticles were prepared through an epoxide-mediated alkalinization process and used as NBBs to construct microspheres. The spherical particles in micrometer scale were synthesized by an aerosol-assisted assembly of the NBBs dispersed in a solvent, in the presence of supramolecular templates. It was found that controlling the crystallization as well as the surface philicity permits to yield the NBB with an adequately small size and interparticle interactions that generate self-assembled mesoporous microspheres akin to those obtained in NBB-based mesoporous thin films. The preparation technique demonstrated here is highly versatile; templated mesoporous microspheres with various chemical compositions of nickel-based layered double hydroxides were successfully obtained. |
|
言語 |
en |
| 内容記述 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
The present work was partially supported by JSPS KAKENHI, JSPS bilateral program, LNLS proposal SAXS1 18927, ANPCyT (PICT 2012-2087 and 2015-3526), UBACyT (20020130100610BA), Hitachi Metals Materials Science Foundation, The Sumitomo Foundation, and Izumi Science and Technology Foundation. |
| 出版者 |
|
|
出版者 |
Springer |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AO |
|
出版タイプResource |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| 関連情報 |
|
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1007/s10971-018-4810-z |
| 関連情報 |
|
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
https://doi.org/10.1007/s10971-018-4810-z |
| 収録物識別子 |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
1573-4846 |
| 開始ページ |
|
|
開始ページ |
216 |
| 書誌情報 |
en : Journal of Sol-Gel Science and Technology
巻 89,
p. 216-224,
発行日 2018-09-15
|
| 旧ID |
53539 |
JSolGelSciTech_89_216.pdf (1.7 MB)
