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Geometric and Electronic Structures of Dibenzo-15-Crown-5 Complexes with Alkali Metal Ions Studied by UV Photodissociation and UV-UV Hole-Burning Spectroscopy
https://hiroshima.repo.nii.ac.jp/records/2007493
https://hiroshima.repo.nii.ac.jp/records/20074933a761f81-24f8-4327-8e0c-9d65bd6bae5c
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
JPhysChemA_2017_121_954.pdf (4.1 MB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2023-03-18 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Geometric and Electronic Structures of Dibenzo-15-Crown-5 Complexes with Alkali Metal Ions Studied by UV Photodissociation and UV-UV Hole-Burning Spectroscopy | |||||||||||
| 言語 | en | |||||||||||
| 作成者 |
Inokuchi, Yoshiya
× Inokuchi, Yoshiya
× Kida, Motoki
× Ebata, Takayuki
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| アクセス権 | ||||||||||||
| アクセス権 | open access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | Copyright (c) 2017 American Chemical Society | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Journal of Physical Chemistry A', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpca.6b09653. | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | |||||||||||
| 主題 | ||||||||||||
| 主題Scheme | NDC | |||||||||||
| 主題 | 430 | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述 | We measure UV photodissociation (UVPD) and UV-UV hole-burning (HB) spectra of dibenzo-15-crown-5 (DB15C5) complexes with alkali metal ions, M+•DB15C5 (M = Li, Na, K, Rb, and Cs), under cold (~10 K) conditions in the gas phase. The UV-UV HB spectra of the M+•DB15C5 (M = K, Rb, and Cs) complexes indicate that there is one dominant conformation for each complex except the Na+•DB15C5 complex, which has two conformers with a comparable abundance ratio. It was previously reported that the M+•(benzo-15-crown-5) (M+•B15C5, M = K, Rb, and Cs) complexes each have three conformers. Thus, the attachment of one additional benzene ring to the crown cavity of benzo-15-crown-5 reduces conformational flexibility, giving one dominant conformation for the M+•DB15C5 (M = K, Rb, and Cs) complexes. In the UVPD spectra of the K+•DB15C5, Rb+•DB15C5, and Cs+•DB15C5 complexes, the S1–S0 and S2–S0 transitions are observed independently at different positions with different vibronic structures. The spectral features are substantially different from those of the K+•(dibenzo-18-crown-6) (K+•DB18C6) complex, which belongs to C2v point group and exhibits the exciton splitting with an interval of 2.7 cm–1. The experimental and theoretical results suggest that in the M+•DB15C5 complexes the two benzene rings are not symmetrically equivalent with each other, and the S1–S0 and S2–S0 electronic excitations are almost localized in one of the benzene rings. The electronic interaction energy between the two benzene chromophores is compared between the K+•DB15C5 and K+•DB18C6 complexes by quantum chemical calculations. The interaction energy of the K+•DB15C5 complex is estimated to be less than a half of the K+•DB18C6 complex (~30 cm–1) due to less suitable relative angles between the transition dipole moments of the two benzene chromophores in K+•DB15C5. | |||||||||||
| 言語 | en | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述タイプ | Other | |||||||||||
| 内容記述 | This work was partly supported by JSPS KAKENHI Grant Number 16H04098. | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | American Chemical Society | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | AO | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_b1a7d7d4d402bcce | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | 10.1021/acs.jpca.6b09653 | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | PMID | |||||||||||
| 関連識別子 | 28099814 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 1089-5639 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 1520-5215 | |||||||||||
| 開始ページ | ||||||||||||
| 開始ページ | 954 | |||||||||||
| 書誌情報 |
Journal of Physical Chemistry A Journal of Physical Chemistry A 巻 121, 号 5, p. 954-962, 発行日 2017-01-18 |
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| 旧ID | 45932 | |||||||||||
