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Synthesis of anilinonaphthoquinone-based nickel complexes and their application for olefin polymerization
https://hiroshima.repo.nii.ac.jp/records/2007451
https://hiroshima.repo.nii.ac.jp/records/20074517e1cbf8b-509b-4a2d-a271-08dc23f2ccdd
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
JOrganoChem_692_5183.pdf (243.6 KB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2023-03-18 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Synthesis of anilinonaphthoquinone-based nickel complexes and their application for olefin polymerization | |||||||||||
| 言語 | en | |||||||||||
| 作成者 |
Okada, Mitsuhiro
× Okada, Mitsuhiro
× Nakayama, Yuushou
× Shiono, Takeshi
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| アクセス権 | ||||||||||||
| アクセス権 | open access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | Copyright(c) 2007 Elsevier Science SA | |||||||||||
| 主題 | ||||||||||||
| 主題Scheme | Other | |||||||||||
| 主題 | ethylene polymerization | |||||||||||
| 主題 | ||||||||||||
| 主題Scheme | Other | |||||||||||
| 主題 | nickel catalyst | |||||||||||
| 主題 | ||||||||||||
| 主題Scheme | Other | |||||||||||
| 主題 | polyethylene | |||||||||||
| 主題 | ||||||||||||
| 主題Scheme | NDC | |||||||||||
| 主題 | 430 | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述 | A series of anilinonaphthoquinone-based nickel complexes, Ni(C10H5O2NAr)(Ph)(PPh3) (Ar = C6H3-2,6-Me (1c); Ar = C6H2-2,4,6-Me (2c); Ar = C6H3-2,6-Et (3c)), were synthesized and the structures of 1c-3c were confirmed by single crystal X-ray analyses. The anilinonaphthoquinone-ligated nickel complexes activated with B(C6F5)(3) showed high activities for ethylene polymerization at 40 degrees C under atmospheric pressure of ethylene and gave polyethylene with long chain branches and short chain branches. The activity of these systems was decreased by lowering polymerization temperature accompanied by increase in molecular weight. The number of the chain branches was also decreased with lowering polymerization temperature and increasing the bulkiness of the ligand. | |||||||||||
| 言語 | en | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | Elsevier Science SA | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | AO | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_b1a7d7d4d402bcce | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | 10.1016/j.jorganchem.2007.07.049 | |||||||||||
| 関連情報 | ||||||||||||
| 関連タイプ | isVersionOf | |||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | http://dx.doi.org/10.1016/j.jorganchem.2007.07.049 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 0022-328X | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||
| 収録物識別子 | AA00704122 | |||||||||||
| 開始ページ | ||||||||||||
| 開始ページ | 5183 | |||||||||||
| 書誌情報 |
Journal of Organometallic Chemistry Journal of Organometallic Chemistry 巻 692, 号 23, p. 5183-5189, 発行日 2007-11 |
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| 旧ID | 21455 | |||||||||||
