Item type |
デフォルトアイテムタイプ_(フル)(1) |
公開日 |
2023-03-18 |
タイトル |
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タイトル |
Nucleation on active centers in confined volumes |
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言語 |
en |
作成者 |
Kožíšek, Zdeněk
Hikosaka, Masamichi
Okada, Kiyoka
Demo, Pavel
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アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
権利情報 |
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権利情報 |
(c) 2012 American Institute of Physics |
主題 |
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主題Scheme |
NDC |
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主題 |
430 |
内容記述 |
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内容記述 |
Kinetic equations describing nucleation on active centers are solved numerically to determine the number of supercritical nuclei, nucleation rate, and the number density of nuclei for formation both of droplets from vapor and also crystalline phase from vapor, solution, and melt. Our approach follows standard nucleation model, when the exhaustion of active centers is taken into account via the boundary condition, and thus no additional equation (expressing exhaustion of active centers) is needed. Moreover, we have included into our model lowering of supersaturation of a mother phase as a consequence of the phase transition process within a confined volume. It is shown that the standard model of nucleation on active centers (Avrami approach) gives faster exhaustion of active centers as compared with our model in all systems under consideration. Nucleation rate (in difference to standard approach based on Avrami model) is equal to the time derivative of the total number of nuclei and reaches some maximum with time. At lower nucleation barrier (corresponding to higher initial supersaturation or lower wetting angle of nucleus on the surface of active center) the exhaustion of active centers is faster. Decrease in supersaturation of the mother phase is faster at higher number of active centers. |
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言語 |
en |
出版者 |
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出版者 |
American Institute of Physics |
言語 |
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言語 |
eng |
資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
出版タイプ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
関連情報 |
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識別子タイプ |
DOI |
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関連識別子 |
10.1063/1.4705436 |
関連情報 |
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識別子タイプ |
DOI |
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関連識別子 |
http://dx.doi.org/10.1063/1.4705436 |
収録物識別子 |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
0021-9606 |
収録物識別子 |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA00694991 |
開始ページ |
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開始ページ |
164506 |
書誌情報 |
Journal of Chemical Physics
Journal of Chemical Physics
巻 136,
号 16,
p. 164506,
発行日 2012
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旧ID |
33888 |