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He*(23S) penning ionization of H2S. II. Formation of the SH+(A3∏) and H2S +(Ã2A1) ions
https://hiroshima.repo.nii.ac.jp/records/2007261
https://hiroshima.repo.nii.ac.jp/records/20072618149fa50-5c29-4f73-9aaf-60fa3170b958
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
JChemPhys_119_5882.pdf (187.9 KB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||||||
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| 公開日 | 2023-03-18 | |||||||||||
| タイトル | ||||||||||||
| タイトル | He*(23S) penning ionization of H2S. II. Formation of the SH+(A3∏) and H2S +(Ã2A1) ions | |||||||||||
| 言語 | en | |||||||||||
| 作成者 |
Tokue, Ikuo
× Tokue, Ikuo
× Yamasaki, Katsuyoshi
× Nanbu, Shinkoh
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| アクセス権 | ||||||||||||
| アクセス権 | open access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | Copyright (c) 2003 American Institute of Physics. | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述 | Emissions in the 200–750 nm region produced by the collision of He*(2 3S) with H2S were studied under single-collision conditions. The hydrogen Balmer lines and the SH+(A 3Π–X 3Σ-) and H2S+(A˜ 2A1–X˜ 2B1) bands were assigned. The total emission cross section (σem) was evaluated to be (1.7±0.3)×10-20 m2 at a collision energy of 150 meV. The σems of the SH+(A–X) and H2S+(A˜ –X˜ ) bands decreased with increase in the collision energy in the 115–200 meV range, indicating that attractive forces are effective for the incident channels with regard to the formation of these species. The rotational distribution of SH+(A 3Π,ν'=0) is represented by a Boltzmann temperature of 870±80 K. The H2S+(A˜ 2A1–X˜ 2B1) emission, which was assigned for the first time in the Penning ionization of H2S, primarily consists of the bending progressions. The internal populations of H2S+(A˜ ) were analyzed using the vibrational energies and Einstein's A coefficients calculated in this study. The details of the calculation and derived spectroscopic constants are reported in the accompanying paper, Paper I. The populations obtained for the bending vibration (ν' 2) of H2S+(A˜ ) show an inverted distribution with a peak at ν' 2=3. This distribution is shifted lower compared that with a peak at ν' 2=4 – 5 observed by He*(2 3S) Penning ionization electron spectroscopy and that with a peak at ν' 2=6 – 7 predicted by the theoretical Franck–Condon factors for the H2S(X˜ )–H2S1(A˜ ) ionization. The origin of the difference is discussed concerning the formation mechanism of H2S1(A˜ 2A1). | |||||||||||
| 言語 | en | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | American Institute of Physics | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | VoR | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | 10.1063/1.1602064 | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | http://dx.doi.org/10.1063/1.1602064 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 0021-9606 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||
| 収録物識別子 | AA00694991 | |||||||||||
| 開始ページ | ||||||||||||
| 開始ページ | 5882 | |||||||||||
| 書誌情報 |
Journal of Chemical Physics Journal of Chemical Physics 巻 119, 号 12, p. 5882-5888, 発行日 2003-09-22 |
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| 旧ID | 19243 | |||||||||||
