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He*(23S) Penning ionization of H2S. I. Theoretical Franck-Condon factors for the H2S(X̃ 1A1, v′ = 0)→H2S+ (X̃2B1, Ã2A1) ionization and H2S+(Ã-X̃) transition
https://hiroshima.repo.nii.ac.jp/records/2007260
https://hiroshima.repo.nii.ac.jp/records/20072602516bf15-8ef3-4306-ae88-63c471e6461d
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
JChemPhys_119_5874.pdf (132.1 KB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||||||
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| 公開日 | 2023-03-18 | |||||||||||
| タイトル | ||||||||||||
| タイトル | He*(23S) Penning ionization of H2S. I. Theoretical Franck-Condon factors for the H2S(X̃ 1A1, v′ = 0)→H2S+ (X̃2B1, Ã2A1) ionization and H2S+(Ã-X̃) transition | |||||||||||
| 言語 | en | |||||||||||
| 作成者 |
Tokue, Ikuo
× Tokue, Ikuo
× Yamasaki, Katsuyoshi
× Nanbu, Shinkoh
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| アクセス権 | ||||||||||||
| アクセス権 | open access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | Copyright (c) 2003 American Institute of Physics. | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述 | In order to elucidate the ionization dynamics, in particular the vibrational distribution, of H2S+(A˜ ) produced by the Penning ionization of H2S with He*(2 3S) atoms, the Franck–Condon factors (FCFs) were presented for the H2S(X˜ )!H2S+(X˜ ,A˜ ) ionization and the H2S+(A˜ –X˜ ) transition, and Einstein's A coefficients were presented for the latter transition. The FCFs were obtained by quantum vibrational calculations using the global potential energy surfaces (PESs) of H2S(X˜ 1A1) and H2S+(X˜ 2B1 ,A˜ 2A1 ,B˜ 2B2) electronic states. The global PESs were determined by the multireference configuration interaction calculations with the Davidson correction and the interpolant moving least squares method combined with the Shepard interpolation. The obtained FCFs exhibit that the H2S+(X˜ ) state primarily populates the vibrational ground state since its equilibrium geometry is almost equal to that of H2S(X˜ ), while the bending mode (ν 2) is strongly enhanced for the H2S+(A˜ ) state; the maximum in the population is around ν 2=6 – 7. In the same manner, the bending progressions are expected to consist of the great part of the H2S+(A˜ –X˜ ) emission. A detailed comparison with the experimental study for this system is reported in the accompanying paper, Paper II. | |||||||||||
| 言語 | en | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | American Institute of Physics | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | VoR | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | 10.1063/1.1602063 | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | http://dx.doi.org/10.1063/1.1602063 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 0021-9606 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||
| 収録物識別子 | AA00694991 | |||||||||||
| 開始ページ | ||||||||||||
| 開始ページ | 5874 | |||||||||||
| 書誌情報 |
Journal of Chemical Physics Journal of Chemical Physics 巻 119, 号 12, p. 5874-5881, 発行日 2003-09-22 |
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| 旧ID | 19242 | |||||||||||
