Item type |
デフォルトアイテムタイプ_(フル)(1) |
公開日 |
2023-03-18 |
タイトル |
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タイトル |
The valence state of Yb ion in YbInAu2 compound at high pressure determined by x-ray diffraction and x-ray absorption near edge structure measurements |
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言語 |
en |
作成者 |
Fuse, Akinori
Nakamoto, Go
Ishimatsu, Naoki
Kurisu, Makio
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アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
権利情報 |
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権利情報 |
Copyright (c) 2006 American Institute of Physics. |
内容記述 |
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内容記述 |
X-ray diffraction patterns and LIII-edge x-ray absorption near edge structure (XANES) spectra of YbInAu2 and LuInAu2 compounds have been measured at high pressure and room temperature using a diamond anvil cell and a synchrotron radiation at SPring-8. YbInAu2 is more compressible at pressures lower than 4 GPa than above it; the evaluated bulk modulus by Birch-type equation of state is 54.7 GPa which is one-half of that of the LuInAu2 (112.5 GPa). The mean valence v¯ of Yb ion in YbInAu2 determined by the XANES measurement is an increasing function of pressure: 2.71(2) at normal pressure and 2.94(2) at 10 GPa. The rate of increase in v¯ with pressure is two times larger at pressures below 4 GPa than that above 4 GPa. However, the v¯ is described by a linear increasing function of the lattice compression: v¯ =v¯0+2.9|ΔV/V0| where v¯0 is 2.71. The extrapolation to the trivalent state gives the critical pressure of 13 GPa. |
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言語 |
en |
出版者 |
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出版者 |
American Institute of Physics |
言語 |
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言語 |
eng |
資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
出版タイプ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
関連情報 |
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識別子タイプ |
DOI |
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関連識別子 |
10.1063/1.2335388 |
関連情報 |
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識別子タイプ |
DOI |
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関連識別子 |
http://dx.doi.org/10.1063/1.2335388 |
収録物識別子 |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
0021-8979 |
収録物識別子 |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA00693547 |
書誌情報 |
Journal of Applied Physics
Journal of Applied Physics
巻 100,
号 4,
発行日 2006-08-25
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旧ID |
18649 |