| Item type |
デフォルトアイテムタイプ_（フル）(1) |
| 公開日 |
2025-01-30 |
| タイトル |
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|
タイトル |
Thermal Structure Transformation of Methylammonium Vanadate and it's Application as a Negative Staining Reagent for Observing SARS-CoV-2 |
|
言語 |
en |
| 作成者 |
Sukmana, Ndaru Candra
Sugiarto
Shinogi, Jun
Yamamoto, Akima
Higashiura, Akifumi
Sakaguchi, Takemasa
Sadakane, Masahiro
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| アクセス権 |
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|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
|
|
言語 |
en |
|
権利情報 |
This is the peer reviewed version of the following article: N. C. Sukmana Sugiarto, J. Shinogi, A. Yamamoto, A. Higashiura, T. Sakaguchi, M. Sadakane, Eur. J. Inorg. Chem. 2022, e202200322., which has been published in final form at https://doi.org/10.1002/ejic.202200322. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. |
| 権利情報 |
|
|
言語 |
en |
|
権利情報 |
This is not the published version. Please cite only the published version. |
| 権利情報 |
|
|
言語 |
ja |
|
権利情報 |
この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。 |
| 主題 |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
Negative staining reagents |
| 主題 |
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言語 |
en |
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主題Scheme |
Other |
|
主題 |
Polyoxometalates |
| 主題 |
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|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
Polyoxovanadates |
| 主題 |
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|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
Structure elucidation |
| 主題 |
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|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
Thermochemistry |
| 内容記述 |
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|
内容記述 |
The solid-state thermal structure transformation of methylammonium vanadate, (CH3NH3)VO3, from −150 °C to 350 °C is reported. Variable-temperature X-ray single-crystal structure analysis at 23, 0, −50, −100, and −150 °C reveal (CH3NH3)VO3 comprises of methylammonium cations and “snake-like" ([VO3]−)n anion chains propagating along the c-direction in the Pna21 space group. In between −150 and −100 °C, we observe a reversible structural transformation due to the re-orientation of the methylammonium cations in the crystal packing, which is also confirmed by the reversible profiles observed in differential scanning calorimetry. The methylammonium vanadate is stable until at ca. 100 °C and further heating releases methylamine and water and V2O5 is formed at ca. 275 °C . Furthermore, we show that the methylammonium vanadate can be used as a negative staining reagent for visualizing SARS-CoV-2, allowing us to discern the spike proteins from the body of the virus using transmission electron microscopy. |
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言語 |
en |
| 内容記述 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
This study was supported by JST A-STEP (Grant Number JPMJTM20RF), the International Network on Polyoxometalate Science at Hiroshima University, and the JSPS Core-to-Core program. N. C. S. would like to thank the financial support from the Osimo Scholarship and Program for Developing and Supporting the Next Generation of Innovative Researchers at Hiroshima University. |
|
言語 |
en |
| 出版者 |
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|
出版者 |
Wiley |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
https://doi.org/10.1002/ejic.202200322 |
| 開始ページ |
|
|
開始ページ |
e202200322 |
| 書誌情報 |
en : European Journal of Inorganic Chemistry
巻 2022,
号 26,
p. e202200322,
発行日 2022-09-09
|
| 旧ID |
56197 |
EJIC_26.pdf (1.9 MB)
