| Item type |
デフォルトアイテムタイプ_（フル）(1) |
| 公開日 |
2023-03-18 |
| タイトル |
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タイトル |
Photodissociation spectroscopy of (benzene-toluene)+. Charge delocalization in the hetero-dimer ion |
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言語 |
en |
| 作成者 |
Ohashi, Kazuhiko
Nakane, Youko
Inokuchi, Yoshiya
Nakai, Yasuhiro
Nishi, Nobuyuki
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| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
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権利情報 |
(c) 1998 Elsevier Science B.V. All rights reserved. |
| 主題 |
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主題Scheme |
NDC |
|
主題 |
430 |
| 内容記述 |
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内容記述 |
The electronic spectrum of the benzene–toluene hetero-dimer ion is measured in the 380–1400 nm region. The spectrum shows intense bands around 1175 and 670 nm and a weaker band around 920 nm, which correspond to charge resonance (CR) bands of homodimer ions. The observation indicates that the positive charge stays on the benzene part in some probability, although the ionization potential of benzene is 0.4162 eV higher than that of toluene. A local excitation band (LE) is observed around 420 nm, where a π←πtransition is locally excited in the charged benzene or toluene molecule. On the basis of the position of the CR-like bands as well as the intensity of the LE band relative to that of homo-dimer ions, the probability of finding the charge on the benzene molecule is analyzed to be approximately 36 %. |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Other |
|
内容記述 |
This work was supported in part by a Grant-in-Aid for research program (07740465) from the Ministry of Education, Science, Sports and Culture of Japan. |
| 内容記述 |
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内容記述タイプ |
Other |
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内容記述 |
This is a postprint of an article published by Elsevier B.V. in Chemical physics, 1998, available online: http://doi.org/10.1016/S0301-0104(98)00313-9 |
| 出版者 |
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出版者 |
Elsevier B.V. |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
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出版タイプ |
AO |
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出版タイプResource |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| 関連情報 |
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識別子タイプ |
DOI |
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関連識別子 |
10.1016/S0301-0104(98)00313-9 |
| 関連情報 |
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関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
|
|
関連識別子 |
http://doi.org/10.1016/S0301-0104(98)00313-9 |
| 収録物識別子 |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
0301-0104 |
| 収録物識別子 |
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収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA00602111 |
| 開始ページ |
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開始ページ |
429 |
| 書誌情報 |
Chemical physics
Chemical physics
巻 239,
号 1–3,
p. 429-436,
発行日 1998-12-15
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| 旧ID |
38225 |
Chem_Phys_1998_239_429.pdf (199.4 KB)
