| Item type |
デフォルトアイテムタイプ_（フル）(1) |
| 公開日 |
2023-03-18 |
| タイトル |
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|
タイトル |
Infrared photodissociation spectra and solvation structures of Cu+(H2O)n (n = 1-4) |
|
言語 |
en |
| 作成者 |
Iino, Takuro
Ohashi, Kazuhiko
Mune, Yutaka
Inokuchi, Yoshiya
Judai, Ken
Nishi, Nobuyuki
Sekiya, Hiroshi
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| アクセス権 |
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|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
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|
権利情報 |
(c) 2006 Elsevier B.V. All rights reserved. |
| 主題 |
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主題Scheme |
NDC |
|
主題 |
430 |
| 内容記述 |
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内容記述 |
Coordination and solvation structures of the Cu+(H2O)n ions with n = 1–4 are studied by infrared photodissociation spectroscopy and density functional theory calculations. Hydrogen bonding between H2O molecules is detected in Cu+(H2O)3 and Cu+(H2O)4 through a characteristic change in the position and intensity of OH-stretching transitions. The third and fourth waters prefer hydrogen-bonding sites in the second solvation shell rather than direct coordination to Cu+. The infrared spectroscopy verifies that the gas-phase coordination number of Cu+ in Cu+(H2O)n is two and the resulting linearly coordinated structure acts as the core of further solvation processes. |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Other |
|
内容記述 |
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2006, available online: http://doi.org/10.1016/j.cplett.2006.06.036 |
| 内容記述 |
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内容記述タイプ |
Other |
|
内容記述 |
This work was supported in part by “Nanotechnology Support Project" and Grant-in-Aid for Scientific Research (No. 17550014) of the Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan. |
| 出版者 |
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出版者 |
Elsevier B.V. |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AO |
|
出版タイプResource |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| 関連情報 |
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|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1016/j.cplett.2006.06.036 |
| 関連情報 |
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|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
|
|
関連識別子 |
http://doi.org/10.1016/j.cplett.2006.06.036 |
| 収録物識別子 |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0009-2614 |
| 開始ページ |
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|
開始ページ |
24 |
| 書誌情報 |
Chemical Physics Letters
Chemical Physics Letters
巻 427,
号 1–3,
p. 24-28,
発行日 2006-08-18
|
| 旧ID |
38236 |
ChemPhysLett_2006_427_24.pdf (833.6 KB)
