ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

  1. 広島大学博士論文
  2. 2012年度以前

ベスビアナイトの結晶化学と結晶構造

https://doi.org/10.11501/3079835
https://doi.org/10.11501/3079835
7811073e-2863-4827-9ec2-22b064a49365
名前 / ファイル ライセンス アクション
diss_ko1219.pdf diss_ko1219.pdf (43.4 MB)
Item type デフォルトアイテムタイプ_(フル)(1)
公開日 2023-03-18
タイトル
タイトル Crystal Chemistry and Structure of Vesuvianite
言語 en
タイトル
タイトル ベスビアナイトの結晶化学と結晶構造
言語 ja
作成者 大川, 真紀雄

× 大川, 真紀雄

ja 大川, 真紀雄

en Ohkawa, Makio

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利情報
権利情報 Copyright(c) by Author
主題
主題Scheme NDC
主題 450
内容記述
内容記述 The chemical variation of vesuvianite samples from 16 different localities, eleven in Japan, two in Norway, one in Canada, Pakistan, and Russia, have been examined using electron-microprobe analyses. For some of selected samples boron content was also examined. Results of analyses were reduced to formula unit on the basis of 50 cations excluding B. The crystal structures of six high-symmetry (P4/nnc) vesuvianite from Japan and three low-symmetry (non-P4/nnc) vesuvianites from Japan, Pakistan and Norway were determined by single-crystal X-ray diffraction method. The nine crystals have the following cell parameters; a = 15.568(2), 15.559(3), 15.528(3), 15.472(2), 15.564(2), 15.559(3), 15.572(2), 15.759(1), 15.563(2); c = 11.790(1), 11.797(2), 11.755(2), 11.754(1), 11.841(1), 11.826(2), 11.833(2), 11.727(1), 11.818(1) Å, respectively. The structure refinements were carried out in the space group P4/nne, P4/n and P4nc. The final R indices for 1821, 1493, 1357, 1415, 3024, 3743, 2053, 1745 and 1873 independent reflections are 0.038, 0.031, 0.040, 0.032, 0.063, 0.082, 0.038, 0.039 and 0.042, respectively. The EXAFS method was also used to investigate the local environment of the Cu and Mn ions in the crystal structure of vesuvianites from Norway and Japan. The chemical analyses of low-symmetry vesuvianites indicate a very small amount of F and almost negligible Cl while high-symmetry one contains a considerable amount of F and Cl. The high-symmetry vesuvianite can contain Cl- ions preferentially occupying the O(10) site which is split into two sites; one is occupied by Cl- and the other by F. The chemical compositions of high-symmetry vesuvianites are more variable than those of low-symmetry vesuvianites. The ordering of cation and vacancy in the two alternately and statistically occupied sites in a unit cell causes the lowering of the symmetry from the space group P4/nnc to P4/n or P4nc. The ordering scheme of P4nc structure is firstly confirmed in this paper. In the three low-symmetry vesuvianites, the refined site occupancy ratios for occupied (B(a) and C(a)) and vacant sites (B(b) and C(b)) are 63:37, 62:38 and 92:8 (%), respectively, and the values suggest that the ordering in these crystals is not complete. In low-symmetry vesuvianite, the satisfaction of the local charge balance on O(10) anions requires alternate occupancy of oxygen and hydroxyl with an associated hydrogen bond and ordering sequences of cations. In Cl- and F-bearing high-symmetry vesuvianite, on the other hand, occupying of Cl and F in O(10) sites interrupts the sequences of cations and vacancies along the fourfold rotation axes. Boron-bearing vesuvianite from Russia contain more Mg and less Al than those of boron-free vesuvianite. Boron occupies the additional cation sites, tetrahedrally coordinated site at the 8h position and triangularly coordinated site at the 2a position. The excess of the scattering power at these sites derived from the measured amounts of boron indicates that some elements other than boron should occupy in boron positions.
言語 en
内容記述
内容記述タイプ TableOfContents
内容記述 CONTENTS I.Introduction / p1 II.Experimental / p5  A.Specimens used in this study / p5  B.Electron-microprobe analysis / p5  C.Structural analyses / p5 III.Result and discussion / p10  A.Chemistry / p10  B.Structure / p12 IV.Conclusion / p42 References / p44
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_db06
資源タイプ doctoral thesis
出版タイプ
出版タイプ NA
出版タイプResource http://purl.org/coar/version/c_be7fb7dd8ff6fe43
ID登録
ID登録 10.11501/3079835
ID登録タイプ JaLC
関連情報
関連タイプ references
関連名称 Journal of Science of the Hiroshima University, Series C, Vol. 10, No.1 (1994)
開始ページ
開始ページ 1
書誌情報
p. 1
学位授与番号
学位授与番号 甲第1219号
学位名
言語 ja
学位名 博士(理学)
学位名
言語 en
学位名 Physical Science
学位授与年月日
学位授与年月日 1994-03-25
学位授与機関
学位授与機関識別子Scheme kakenhi
学位授与機関識別子 15401
言語 ja
学位授与機関名 広島大学
学位授与機関
言語 en
学位授与機関名 Hiroshima University
旧ID 31950
戻る
0
views
See details
Views

Versions

Ver.1 2025-02-21 02:02:44.286995
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR 2.0
  • OAI-PMH JPCOAR 1.0
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3