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  1. 広島大学博士論文
  2. 2012年度以前

Extended X-ray Absorption Fine Structure Studies of Si-Ge Alloys with Synchrotron Radiation

https://hiroshima.repo.nii.ac.jp/records/2005291
https://hiroshima.repo.nii.ac.jp/records/2005291
1ff0b665-5371-4e91-8c32-587ceaea8168
名前 / ファイル ライセンス アクション
diss_otsu1773.pdf diss_otsu1773.pdf (2.6 MB)
Item type デフォルトアイテムタイプ_(フル)(1)
公開日 2023-03-18
タイトル
タイトル 放射光を用いたEXAFS法によるSi-Ge合金の研究
言語 en
タイトル
タイトル Extended X-ray Absorption Fine Structure Studies of Si-Ge Alloys with Synchrotron Radiation
言語 ja
作成者 梶山, 博司

× 梶山, 博司

ja 梶山, 博司

en Kajiyama, Hiroshi

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アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利情報
権利情報 Copyright(c) by Author
主題
主題Scheme NDC
主題 560
内容記述
内容記述 Extended X-ray absorption fine structure (EXAFS) has been developed to a useful tool for determining the local bonding structure around an X-ray absorbing atom.EXAFS spectra are usually interpreted by a simple formula derived from an electron scattering theory, with the plane wave approximation. A curve-fitting technique gives plausible bond lengths, where the absorbing edge energy, E₀, is used as one of the parameters. Model compounds are necessary to get the reliable structure in most cases. However, in the case of binary or ternary compounds, it is unreasonable to yield different values of E₀ for different neighboring atoms through the curve-fitting procedure. Furthermore, it is difficult to find good model compounds. A new method has been developed here tor the EXAFS analysis, which is based on the spherical wave approach for emitted electrons. This method is proved to give a reliable structure even without model compounds. Ge K-edge EXAFS spectra have been measured for amorphous-Si₁-xGex:H (x=0.27, 0.36, 0.38, o.47, 0.56, 1.0) and crystalline-Si₁-xGex (x=0.2, 0.39, 0.59, 0.81, 1.0), using synchrotron radiation as the photon source.Spectra were analyzed by the newly developed method without using model compounds and by fixing the E₀ value at the steepest point of the absorption edge. Obtained results show that Ge-Ge and Ge-Si bond lengths of amorphous- Si₁-xGex:H are 2.46Å and 2.41Å, respectively, irrespective of Ge concentration. These bond lengths can be interpreted by the sum of the atomic radii of constituent elements as pointed by Bragg and later by Pauling. As for the case of crystalline-Si₁-xGex, the resulted bond lengths of Ge-Ge and Ge-Si were almost similar to the corresponding bond lengths in amorphous-Si₁-xGex:H. The difference of crystalline and amorphous alloys should be only interpreted by the difference of bond angle distortion. A study on the coordination around a Ge atom in amorphous-Si₁-xGe:H revealed that Ge and Si atoms are randomly mixed in the compositional range below 40 atomic percent. In the amorphous alloys with higher Ge content, the coodinations of Ge atoms surrounding a central Ge atoms is 15-20 percent higher than expected for a random mixture, suggesting a structural inhomogeneity in Ge-rich region. Whereas in crystalline Si₁-xGex, it is found that Ge and Si atoms are randomly mixed in the studied compositional range.
言語 en
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_db06
資源タイプ doctoral thesis
学位授与番号
学位授与番号 乙第1773号
学位名
言語 ja
学位名 博士(理学)
学位名
言語 en
学位名 Physical Science
学位授与年月日
学位授与年月日 1988-11-28
学位授与機関
学位授与機関識別子Scheme kakenhi
学位授与機関識別子 15401
言語 ja
学位授与機関名 広島大学
学位授与機関
言語 en
学位授与機関名 Hiroshima University
旧ID 20953
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