ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

  1. 会議発表論文等

A kinetic study on the decay of formic acid produced by the thrmal decomposition of ethyl formate

https://hiroshima.repo.nii.ac.jp/records/2001025
https://hiroshima.repo.nii.ac.jp/records/2001025
32fbfc6d-fc26-43d9-abbd-8dbff12c6fec
名前 / ファイル ライセンス アクション
2005_ISSW25_659_preprint.pdf 2005_ISSW25_659_preprint.pdf (169.0 KB)
Item type デフォルトアイテムタイプ_(フル)(1)
公開日 2023-03-18
タイトル
タイトル A kinetic study on the decay of formic acid produced by the thrmal decomposition of ethyl formate
言語 en
作成者 Okada, Kazumasa

× Okada, Kazumasa

en Okada, Kazumasa

Search repository
Nakamura, M.

× Nakamura, M.

en Nakamura, M.

Search repository
Saito, K.

× Saito, K.

en Saito, K.

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
主題
主題Scheme NDC
主題 430
内容記述
内容記述 The thermal decomposition of ethyl formate diluted in argon has been investigated behind reflected shock waves over the temperature range 1220-1710 K, with a total density of ~ 1.2×10[-5] mol/㎤. Production and decay processes of formic acid were monitored by means of the time-resolved IR emission at 5.7 μm. The emission profiles were analyzed by utilizing the integrated profiles method developed by Yamasaki et al. The resultant first-order decay rate constant is expressed as k=10[9.10] exp (-40.7 Kcal mol[-1]/RT) s[-1], which is in proper agreement with that for the pyrolysis of formic acid obtained by Blades at lawer temperatures, but slightly lower than the estimated expression suggested by Benson and O'Neal. The formation rate for carbon dioxide, however, is found to be greatly accelerated compared to that with formic acid as a starting material, which attributes to the chemical activation of the intermediary produces formic acid.
言語 en
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_5794
資源タイプ conference paper
開始ページ
開始ページ 659
書誌情報 Proceedings of the 25th International Symposium on Shock Waves-ISSW25, 17 - 22 July 2005
Proceedings of the 25th International Symposium on Shock Waves-ISSW25, 17 - 22 July 2005

p. 659-664, 発行日 2005
旧ID 14174
戻る
0
views
See details
Views

Versions

Ver.1 2025-02-18 01:44:52.256972
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR 2.0
  • OAI-PMH JPCOAR 1.0
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3