{"created":"2025-05-27T05:30:55.142749+00:00","id":2040656,"links":{},"metadata":{"_buckets":{"deposit":"2336e87f-60e9-42c3-bc1c-be127f484b67"},"_deposit":{"created_by":7,"id":"2040656","owner":"7","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2040656"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02040656","sets":["1730444907710"]},"author_link":[],"control_number":"2040656","item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Stannylation of alkyl chlorides with stannylpotassium","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hiraoka, Yuta","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nakamoto, Masaaki","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Tsushima, Takumi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yoshida, Hiroto","creatorNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"embargoed access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_f1cf"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"This is a pre-copyedited, author-produced version of an article accepted for publication in Chemistry Letters following peer review. The version of record Yuta Hiraoka, Masaaki Nakamoto, Takumi Tsushima, Hiroto Yoshida, Stannylation of alkyl chlorides with stannylpotassium, Chemistry Letters, Volume 53, Issue 12, December 2024, upae240, is available online at:https://doi.org/10.1093/chemle/upae240.","subitem_rights_language":"en"},{"subitem_rights":"This is not the published version. Please cite only the published version.","subitem_rights_language":"en"},{"subitem_rights":"この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。","subitem_rights_language":"ja"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"alkyl chlorides","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"stannylation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"stannylpotassium","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"A stannylpotassium reagent, generated in situ from a readily available silylstannane and t-BuOK, is demonstrated to react smoothly with an alkyl bromide to give an alkylstannane in high yield. The superior nucleophilicity of the stannylpotassium reagent is illustrated in the efficient stannylative substitution of less reactive alkyl chlorides. Mechanistic studies reveal that the reaction proceeds through an ionic, SN2-type pathway.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Oxford University Press","subitem_publisher_language":"en"}]},"item_1617186660861":{"attribute_name":"Date","attribute_value_mlt":[{"subitem_date_issued_datetime":"2025-12-14","subitem_date_issued_type":"Available"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186901218":{"attribute_name":"Funding Reference","attribute_value_mlt":[{"subitem_award_numbers":{"subitem_award_number":"22H02079","subitem_award_uri":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23K23347/"},"subitem_award_titles":[{"subitem_award_title":"スズ－銅のトランスメタル化を鍵とする革新的炭素－炭素結合形成反応の開発","subitem_award_title_language":"ja"}],"subitem_funder_identifiers":{"subitem_funder_identifier_type":"Crossref Funder","subitem_funder_identifier_type_uri":"https://doi.org/10.13039/501100001691"},"subitem_funder_names":[{"subitem_funder_name":"日本学術振興会","subitem_funder_name_language":"ja"},{"subitem_funder_name":"Japan Society for the Promotion of Science","subitem_funder_name_language":"en"}]},{"subitem_award_numbers":{"subitem_award_number":"23K18544","subitem_award_uri":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-23K18544/"},"subitem_award_titles":[{"subitem_award_title":"オクチルスズを用いる環境保全合成化学：無毒化・分離回収・再利用","subitem_award_title_language":"ja"}],"subitem_funder_identifiers":{"subitem_funder_identifier_type":"Crossref Funder","subitem_funder_identifier_type_uri":"https://doi.org/10.13039/501100001691"},"subitem_funder_names":[{"subitem_funder_name":"日本学術振興会","subitem_funder_name_language":"ja"},{"subitem_funder_name":"Japan Society for the Promotion of Science","subitem_funder_name_language":"en"}]},{"subitem_award_numbers":{"subitem_award_number":"JPMJSP2132"},"subitem_award_titles":[{"subitem_award_title":"広島大学創発的 次世代 研究者育成・支援プログラム","subitem_award_title_language":"ja"}],"subitem_funder_identifiers":{"subitem_funder_identifier_type":"Crossref Funder","subitem_funder_identifier_type_uri":"https://doi.org/10.13039/501100002241"},"subitem_funder_names":[{"subitem_funder_name":"科学技術振興機構","subitem_funder_name_language":"ja"},{"subitem_funder_name":"Japan Science and Technology Agency","subitem_funder_name_language":"en"}]}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2024-12-14","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageStart":"upae240","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"Chemistry Letters","bibliographic_titleLang":"en"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1093/chemle/upae240","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2025-12-14"}],"fileDate":[{"fileDateType":"Available","fileDateValue":"2025-12-14"}],"filename":"CL_53_upae240.pdf","filesize":[{"value":"281 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2040656/files/CL_53_upae240.pdf"},"version_id":"eac6a468-9f13-40f3-88bf-9d73c905ca85"}]},"item_title":"Stannylation of alkyl chlorides with stannylpotassium","item_type_id":"40036","owner":"7","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2025-05-27"},"publish_date":"2025-05-27","publish_status":"0","recid":"2040656","relation_version_is_last":true,"title":["Stannylation of alkyl chlorides with stannylpotassium"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2025-06-04T01:05:53.801647+00:00"}