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  1. 広島大学の刊行物
  2. Journal of science of the Hiroshima University. Series C, Geology and mineralogy
  3. 9巻3号

Metasomatism as a Self-controlled Process

https://doi.org/10.15027/53121
https://doi.org/10.15027/53121
8caa90f7-41c5-4c10-a7df-f83d757de41b
名前 / ファイル ライセンス アクション
JSHUC_9-3_419.pdf JSHUC_9-3_419.pdf (1.6 MB)
Item type デフォルトアイテムタイプ_(フル)(1)
公開日 2023-03-18
タイトル
タイトル Metasomatism as a Self-controlled Process
言語 en
作成者 HOSHINO, Kenichi

× HOSHINO, Kenichi

en HOSHINO, Kenichi

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アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
内容記述
内容記述 Wall-rock alteration by a reaction mineral (Korzhinskii, 1970) has been reinvestigated considering the effect of a varying porosity on the process itself. This is because a limit value of porosity at the replacement front has made it possible to analyze the alteration. In diffusion metasomatism, the porosity decreases toward a fissure due to the "salting out" effect. Strongly dependent upon the porosity, the effective diffusion coefficient decreases toward the fissure. Consequently, a steady state of "constant" concentrations of both replacing and replaced components (∂ci/∂x=0) is almost achieved near the replacement front. The "salting-out" also occurs even in combined diffusion and reverse-infiltration metasomatism. This process may occur in nature. In both cases, the alteration by a reaction mineral causes a porosity decrease in the replaced zone, which in turn hinders the process. In other words, this type of metasomatism is a "self-controlled" process. The formation process of vein-type wollastonite skarn around fissures in limestone, a typical wall-rock alteration, as observed at the Fujigatani mine, SW Japan, has been numerically analyzed based on the thermodynamic assumptions. These consist mainly of constant volume and local equilibrium assumptions, essential in analyzing metasomatic processes. As a result, I have concluded that the porosity is reduced to almost zero near the fissure even when the porosity at a replacement front is extremely large. Hence, the composition of a pore solution of wollastonite zone becomes almost the same as that of the replacement front. This means that the front cannot progress. It should be emphasized that the porosity change acts as an obstacle to the development of the skarn. Therefore, to analyze naturally-occurring metasomatism, we must reexamine the assumptions used since Korzhinskii (1970). The effect of changing porosity on the metasomatism in a solid solution mineral has also been evaluated. I have proved that only a small difference in the intrinsic diffusion coefficients of both replacing and replaced components brings about a large variation of porosity, resulting in quite different concentration profiles compared to those calculated under the constant porosity assumption.
言語 en
出版者
出版者 HIROSHIMA UNIVERSITY
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ departmental bulletin paper
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
ID登録
ID登録 10.15027/53121
ID登録タイプ JaLC
収録物識別子
収録物識別子タイプ ISSN
収録物識別子 0075-4374
収録物識別子
収録物識別子タイプ NCID
収録物識別子 AA00706718
開始ページ
開始ページ 419
書誌情報 Journal of science of the Hiroshima University. Series C, Geology and mineralogy
Journal of science of the Hiroshima University. Series C, Geology and mineralogy

巻 9, 号 3, p. 419-434, 発行日 1992-08-10
旧ID 53121
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