{"created":"2025-02-21T06:10:26.505998+00:00","id":2011608,"links":{},"metadata":{"_buckets":{"deposit":"4e8691be-91af-4773-96be-927cec7038d6"},"_deposit":{"created_by":41,"id":"2011608","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2011608"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02011608","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"3原子分子クラスター内でのラジカルイオンの存在形態の研究 : 赤外光解離分光にもとづいて <総説>","subitem_title_language":"ja"},{"subitem_title":"Electronic and Geometric Structures for Molecular Cluster Ions of Triatomic Molecules Investigated by Infrared Photodissociation Spectroscopy","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"井口, 佳哉","creatorNameLang":"ja"},{"creatorName":"Inokuchi, Yoshiya","creatorNameLang":"en"}],"familyNames":[{"familyName":"井口","familyNameLang":"ja"},{"familyName":"Inokuchi","familyNameLang":"en"}],"givenNames":[{"givenName":"佳哉","givenNameLang":"ja"},{"givenName":"Yoshiya","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2016 日本分光学会"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"Infrared photodissociation spectroscopy","subitem_subject_scheme":"Other"},{"subitem_subject":"Cluster ions","subitem_subject_scheme":"Other"},{"subitem_subject":"Charge-resonance interaction","subitem_subject_scheme":"Other"},{"subitem_subject":"Triatomic molecules","subitem_subject_scheme":"Other"},{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"3原子分子（CO_2, CS_2, OCS, N_2O）によって構成される分子クラスターイオンに対し，赤外光解離分光法（1000-3800cm^-1）を適用し，その振動スペクトルを観測した。このスペクトルには，クラスター中のイオンコアや溶媒分子に特有なバンドが観測された。この赤外光解離スペクトルに基づき，クラスター中に存在するラジカルイオンの存在形態（電子状態，幾何構造，分子間相互作用など）を決定した。また，これらのクラスターイオンの性質と，構成分子のイオン化エネルギー，電子親和力，分子軌道などの性質との関係について考察した。","subitem_description_language":"ja"},{"subitem_description":"We apply infrared photodissociation (IRPD) spectroscopy in the 1000–3800 cm^–1 region for molecular cluster ions consisting of triatomic molecules such as CO_2 , CS_2 , OCS, and N_2O. The IRPD spectra show vibrational bands characteristic of ion core species and solvent molecules, which enables us to determine the electronic and geometric structures of radical ions in the clusters. On the basis of the IRPD results we examine the relation between the structures and properties of constituent molecules such as ionization energy, electron affinity, and molecular orbitals.","subitem_description_language":"en"},{"subitem_description":"この研究は，日本学術振興会科学研究費補助金（18685001，21350016，24655064），三菱化学研究奨励基金，住友財団基礎科学研究助成，倉田記念日立科学技術財団の支援により行われました．","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"日本分光学会"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"0038-7002","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AN00222531","subitem_source_identifier_type":"NCID"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"33"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"41","bibliographicPageStart":"33","bibliographicVolumeNumber":"65","bibliographic_titles":[{"bibliographic_title":"分光研究"},{"bibliographic_title":"分光研究"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.bunkou.or.jp/index.html","subitem_relation_type_select":"URI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"BunkoKenkyu_65_33.pdf","filesize":[{"value":"4.7 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2011608/files/BunkoKenkyu_65_33.pdf"},"version_id":"b02f0f52-cfba-412c-97a1-9dff2f6aa879"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"46216"},"item_title":"3原子分子クラスター内でのラジカルイオンの存在形態の研究 : 赤外光解離分光にもとづいて <総説>","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2011608","relation_version_is_last":true,"title":["3原子分子クラスター内でのラジカルイオンの存在形態の研究 : 赤外光解離分光にもとづいて <総説>"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-22T11:17:00.358796+00:00"}