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Ion core structure in(CS 2 ) n + and(CS 2 ) n − (n=3–10) studied by infrared photodissociation spectroscopy
https://hiroshima.repo.nii.ac.jp/records/2008927
https://hiroshima.repo.nii.ac.jp/records/2008927457a1e11-7049-4549-bee0-6abb7c90468b
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
JChemPhys_2008_128_164319.pdf (271.5 KB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2023-03-18 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Ion core structure in(CS 2 ) n + and(CS 2 ) n − (n=3–10) studied by infrared photodissociation spectroscopy | |||||||||||
| 言語 | en | |||||||||||
| 作成者 |
Kobayashi, Yusuke
× Kobayashi, Yusuke
× Inokuchi, Yoshiya
× Ebata, Takayuki
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| アクセス権 | ||||||||||||
| アクセス権 | open access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | Copyright (c) 2008 American Institute of Physics | |||||||||||
| 主題 | ||||||||||||
| 主題Scheme | NDC | |||||||||||
| 主題 | 430 | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述 | Infrared photodissociation spectra of (CS2)n+ and(CS2)n− with n=3–10 are measured in the 1100–2000 cm−1 region. All the (CS2)n+ clusters exhibit three bands at ∼1410, ∼1490, and ∼1540 cm−1. The intensity of the1540 cm−1 band relative to those of the other bands increases with increasing the cluster size, indicating that the band at 1540 cm−1 is assignable to the antisymmetric CS stretching vibration of solvent CS2 molecules in the clusters. On the basis of density functional theory calculations, the 1410 and 1490 cm−1 bands of (CS2)n+ are assigned to CS stretching vibrations of the C 2S4+ cation core with a C2 form. The (CS2)n− clusters show two bands at around 1215 and 1530 cm−1. Similar to the case of cation clusters, the latter band is ascribed to the antisymmetric CS stretching vibration of solvent CS2 molecules. Vibrational frequency analysis of CS2− and C2S4− suggests that the 1215 cm−1 band is attributed to the antisymmetric CS stretching vibration of the CS2− anion core with a C2v structure. | |||||||||||
| 言語 | en | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | American Institute of Physics | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | VoR | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | 10.1063/1.2913157 | |||||||||||
| 関連情報 | ||||||||||||
| 関連タイプ | isVersionOf | |||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | http://dx.doi.org/10.1063/1.2913157 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 0021-9606 | |||||||||||
| 開始ページ | ||||||||||||
| 開始ページ | 164319-1 | |||||||||||
| 書誌情報 |
The Journal of Chemical Physics The Journal of Chemical Physics 巻 128, 号 16, p. 164319-1-164319-6, 発行日 2008-04-30 |
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| 旧ID | 37642 | |||||||||||
