{"created":"2025-02-21T04:36:42.025482+00:00","id":2008843,"links":{},"metadata":{"_buckets":{"deposit":"9b8ba99a-b86c-44c7-9e3f-5dd5ae8b78c2"},"_deposit":{"created_by":41,"id":"2008843","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2008843"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02008843","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Highly efficient synthesis of [3]rotaxane assisted by preorganisation of pseudorotaxane using bis(crown ether)s","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Iwamoto, Hajime","creatorNameLang":"en"}],"familyNames":[{"familyName":"Iwamoto","familyNameLang":"en"}],"givenNames":[{"givenName":"Hajime","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yawata, Yukimi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Yawata","familyNameLang":"en"}],"givenNames":[{"givenName":"Yukimi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Fukazawa, Yoshimasa","creatorNameLang":"en"}],"familyNames":[{"familyName":"Fukazawa","familyNameLang":"en"}],"givenNames":[{"givenName":"Yoshimasa","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Haino, Takeharu","creatorNameLang":"en"}],"familyNames":[{"familyName":"Haino","familyNameLang":"en"}],"givenNames":[{"givenName":"Takeharu","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2010 Taylor & Francis. This is an electronic version of an article published in \"Supramolecular Chemistry, Volume 22, Issue 11 & 12 November 2010, pages 815 - 826\" Disability and Rehabilitation is available at: http://dx.doi.org/10.1080/10610278.2010.514611"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"[3]rotaxane","subitem_subject_scheme":"Other"},{"subitem_subject":"preorganisation","subitem_subject_scheme":"Other"},{"subitem_subject":"bis(crown ether)","subitem_subject_scheme":"Other"},{"subitem_subject":"olefin metathesis","subitem_subject_scheme":"Other"},{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"The tether-assisted synthesis of [3]rotaxane by olefin metathesis has been studied in detail. Bis(crown ether)s, in which two crown ethers are connected by a linker, were threaded onto ammonium salts bearing a terminal olefin to form pseudorotaxanes. The pseudorotaxanes were converted into tethered rotaxanes in the presence of Grubbs catalyst, followed by removal of the linkers to produce [3]rotaxanes in excellent yields. Preorganisation of the two reactive ends has led to a great improvement in the yield of [3]rotaxanes. The ring strain of the tethered rotaxanes and the flexibility of the pseudorotaxanes were responsible for the formation of the tethered rotaxanes.","subitem_description_language":"en"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Taylor & Francis Ltd"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"1061-0278","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA1100053X","subitem_source_identifier_type":"NCID"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"815"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11-12","bibliographicPageEnd":"826","bibliographicPageStart":"815","bibliographicVolumeNumber":"22","bibliographic_titles":[{"bibliographic_title":"Supramolecular Chemistry"},{"bibliographic_title":"Supramolecular Chemistry"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1080/10610278.2010.514611","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1080/10610278.2010.514611","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"SupramolChem_22_815.pdf","filesize":[{"value":"281.4 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2008843/files/SupramolChem_22_815.pdf"},"version_id":"53894bfd-3ad0-40b0-88d5-22fce6aff240"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"30880"},"item_title":"Highly efficient synthesis of [3]rotaxane assisted by preorganisation of pseudorotaxane using bis(crown ether)s","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2008843","relation_version_is_last":true,"title":["Highly efficient synthesis of [3]rotaxane assisted by preorganisation of pseudorotaxane using bis(crown ether)s"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-22T04:26:26.953260+00:00"}