| Item type |
デフォルトアイテムタイプ_（フル）(1) |
| 公開日 |
2023-03-18 |
| タイトル |
|
|
タイトル |
Photodissociation spectrum of cyanobenzene dimer cation. Absence of intermolecular resonance interaction |
|
言語 |
en |
| 作成者 |
Ohashi, Kazuhiko
Nishiguchi, Masaharu
Inokuchi, Yoshiya
Sekiya, Hiroshi
Nishi, Nobuyuki
|
| アクセス権 |
|
|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
|
|
権利情報 |
(c) VSP 1998 |
| 主題 |
|
|
主題Scheme |
NDC |
|
主題 |
430 |
| 内容記述 |
|
|
内容記述 |
Electronic spectra of a homo-molecular dimer cation, (C6H5CN)2+, are measured by photodissociation spectroscopy in the gas phase. Broad features appeared in the 450–650 nm region are characteristic of π3 → πCN transitions of the C6H5CN+ chromophore. No intense band is observed in the 650–1300 nm region, where other aromatic dimer cations usually show charge resonance bands. Two component molecules of (C6H5CN)2+ cannot take a parallel sandwich configuration suitable for the resonance interaction, because of geometrical constraints due to other stronger interactions. |
|
言語 |
en |
| 内容記述 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
This work was supported in part by a Grant-in-Aid for Scientific Research (No. 09740450) from the Ministry of Education, Science, Sports and Culture of Japan. |
| 内容記述 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
This is a postprint of an article published by Springer Netherlands in Research on Chemical Intermediates, 1998, available online: http://doi.org/10.1163/156856798X00393 |
| 出版者 |
|
|
出版者 |
Springer Netherlands |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AO |
|
出版タイプResource |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| 関連情報 |
|
|
関連タイプ |
isVersionOf |
|
|
関連名称 |
http://doi.org/10.1163/156856798X00393 |
| 関連情報 |
|
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1163/156856798X00393 |
| 収録物識別子 |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0922-6168 |
| 開始ページ |
|
|
開始ページ |
755 |
| 書誌情報 |
Research on Chemical Intermediates
Research on Chemical Intermediates
巻 24,
号 7,
p. 755-764,
発行日 1998-07
|
| 旧ID |
38224 |
ResChemIntermediates_1998_24_755.pdf (172.2 KB)
