{"created":"2025-02-21T04:12:22.071737+00:00","id":2008085,"links":{},"metadata":{"_buckets":{"deposit":"0c1eaab7-9e7a-46ba-834f-a6765aa1a4bd"},"_deposit":{"created_by":41,"id":"2008085","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2008085"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02008085","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Valence, spin, and orbital state of Co ions in one-dimensional Ca3Co2O6 : An x-ray absorption and magnetic circular dichroism study","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Burnus, Tobias","creatorNameLang":"en"}],"familyNames":[{"familyName":"Burnus","familyNameLang":"en"}],"givenNames":[{"givenName":"Tobias","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Hu, Zhiwei","creatorNameLang":"en"}],"familyNames":[{"familyName":"Hu","familyNameLang":"en"}],"givenNames":[{"givenName":"Zhiwei","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Haverkort, Maurits W.","creatorNameLang":"en"}],"familyNames":[{"familyName":"Haverkort","familyNameLang":"en"}],"givenNames":[{"givenName":"Maurits W.","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Cezar, Júlio C.","creatorNameLang":"en"}],"familyNames":[{"familyName":"Cezar","familyNameLang":"en"}],"givenNames":[{"givenName":"Júlio C.","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Flahaut, Delphine","creatorNameLang":"en"}],"familyNames":[{"familyName":"Flahaut","familyNameLang":"en"}],"givenNames":[{"givenName":"Delphine","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Hardy, Vincent","creatorNameLang":"en"}],"familyNames":[{"familyName":"Hardy","familyNameLang":"en"}],"givenNames":[{"givenName":"Vincent","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Maignan, Antoine","creatorNameLang":"en"}],"familyNames":[{"familyName":"Maignan","familyNameLang":"en"}],"givenNames":[{"givenName":"Antoine","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Brookes, Nicholas B.","creatorNameLang":"en"}],"familyNames":[{"familyName":"Brookes","familyNameLang":"en"}],"givenNames":[{"givenName":"Nicholas B.","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Tanaka, Arata","creatorNameLang":"en"}],"familyNames":[{"familyName":"Tanaka","familyNameLang":"en"}],"givenNames":[{"givenName":"Arata","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Hsieh, Hui-Huang","creatorNameLang":"en"}],"familyNames":[{"familyName":"Hsieh","familyNameLang":"en"}],"givenNames":[{"givenName":"Hui-Huang","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Lin, Hong-Ji","creatorNameLang":"en"}],"familyNames":[{"familyName":"Lin","familyNameLang":"en"}],"givenNames":[{"givenName":"Hong-Ji","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Chen Chien-Te","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Tjeng, L. Hao","creatorNameLang":"en"}],"familyNames":[{"familyName":"Tjeng","familyNameLang":"en"}],"givenNames":[{"givenName":"L. Hao","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2006 The American Physical Society."}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"We have investigated the valence, spin, and orbital state of the Co ions in the one-dimensional cobaltate Ca3 Co2 O6 using x-ray absorption and x-ray magnetic circular dichroism at the Co- L2,3 edges. The Co ions at both the octahedral Cooct and trigonal Cotrig sites are found to be in a 3+ state. From the analysis of the dichroism we established a low-spin state for the Cooct and a high-spin state with an anomalously large orbital moment of 1.7 μB at the Cotrig 3+ ions. This large orbital moment along the c -axis chain and the unusually large magnetocrystalline anisotropy can be traced back to the double occupancy of the d2 orbital in trigonal crystal field.","subitem_description_language":"en"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Physical Society"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"1098-0121","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA11187113","subitem_source_identifier_type":"NCID"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"245111-1"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-12-14","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"24","bibliographicPageEnd":"245111-5","bibliographicPageStart":"245111-1","bibliographicVolumeNumber":"74","bibliographic_titles":[{"bibliographic_title":"Physical Review B"},{"bibliographic_title":"Physical Review B"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1103/PhysRevB.74.245111","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1103/PhysRevB.74.245111","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"PhysRevB_74_245111.pdf","filesize":[{"value":"339.1 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2008085/files/PhysRevB_74_245111.pdf"},"version_id":"5682e434-fdb7-4659-ad2e-f52796745c5b"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"19270"},"item_title":"Valence, spin, and orbital state of Co ions in one-dimensional Ca3Co2O6 : An x-ray absorption and magnetic circular dichroism study","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2008085","relation_version_is_last":true,"title":["Valence, spin, and orbital state of Co ions in one-dimensional Ca3Co2O6 : An x-ray absorption and magnetic circular dichroism study"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-22T03:09:15.459030+00:00"}