{"created":"2025-02-21T04:07:14.685332+00:00","id":2007920,"links":{},"metadata":{"_buckets":{"deposit":"03db2168-72e3-439b-aee4-d5de6ee449e0"},"_deposit":{"created_by":41,"id":"2007920","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2007920"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02007920","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yoshida, Hiroto","creatorNameLang":"en"}],"familyNames":[{"familyName":"Yoshida","familyNameLang":"en"}],"givenNames":[{"givenName":"Hiroto","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kimura, Miki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Kimura","familyNameLang":"en"}],"givenNames":[{"givenName":"Miki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Osaka, Itaru","creatorNameLang":"en"}],"familyNames":[{"familyName":"Osaka","familyNameLang":"en"}],"givenNames":[{"givenName":"Itaru","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Takaki, Ken","creatorNameLang":"en"}],"familyNames":[{"familyName":"Takaki","familyNameLang":"en"}],"givenNames":[{"givenName":"Ken","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.7b00058."},{"subitem_rights":"This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Tin fluorides were found to be suitable electrophiles for the copper-catalyzed borylstannylation of terminal alkynes with bis(pinacolato)diboron to afford cis-vic-boryl(stannyl)alkenes straightforwardly. A fluorine atom proved to play a pivotal role in generating a key catalytic intermediate, a borylcopper species, both in the induction period and in the s-bond metathesis step.","subitem_description_language":"en"},{"subitem_description":"This work was financially supported by JSPS KAKENHI Grant Number JP16H01031 in Precisely Designed Catalysts with Customized Scaffolding.","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1520-6041","subitem_source_identifier_type":"ISSN"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"1345"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-03-24","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1351","bibliographicPageStart":"1345","bibliographicVolumeNumber":"36","bibliographic_titles":[{"bibliographic_title":"Organometallics"},{"bibliographic_title":"Organometallics"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.organomet.7b00058","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.organomet.7b00058","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"Organometallics_36_1345.pdf","filesize":[{"value":"677.1 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2007920/files/Organometallics_36_1345.pdf"},"version_id":"d859d221-744a-4e60-adad-86e2d5b38823"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"48763"},"item_title":"Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2007920","relation_version_is_last":true,"title":["Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T11:12:11.725817+00:00"}