{"created":"2025-02-21T04:07:01.111574+00:00","id":2007913,"links":{},"metadata":{"_buckets":{"deposit":"cd5426fb-c1f8-48cf-b499-882bfe597985"},"_deposit":{"created_by":41,"id":"2007913","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2007913"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02007913","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Spontaneous Oxygenation of Siloxy-N-silylketenimines to α-Ketoamides","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sasaki, Michiko","creatorNameLang":"en"}],"familyNames":[{"familyName":"Sasaki","familyNameLang":"en"}],"givenNames":[{"givenName":"Michiko","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ando, Masafumi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ando","familyNameLang":"en"}],"givenNames":[{"givenName":"Masafumi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kawahata, Masatoshi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Kawahata","familyNameLang":"en"}],"givenNames":[{"givenName":"Masatoshi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yamaguchi, Kentaro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Yamaguchi","familyNameLang":"en"}],"givenNames":[{"givenName":"Kentaro","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Takeda, Kei","creatorNameLang":"en"}],"familyNames":[{"familyName":"Takeda","familyNameLang":"en"}],"givenNames":[{"givenName":"Kei","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2016 American Chemical Society"},{"subitem_rights":"This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes."}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"490","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Siloxy-N-silylketenimines generated in situ from Osilyl cyanohydrins were converted to α-ketoamides by brief exposure to air or oxygen. Oxidation under extremely mild conditions can be explained by assuming the intermediacy of a 3-imino-1,2-dioxetane derivative generated via triplet−singlet intersystem crossing after the reaction of siloxy-N-silylketenimines with triplet oxygen.","subitem_description_language":"en"},{"subitem_description":"This research was partially supported by a Grant-in-Aid for Scientific Research (C) 25460015 (M.S.), a Grant-in-Aid for Challenging Exploratory Research 15K14929 (K.T.) from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), the Hoan Sha Foundation (M.S.), the Takeda Science Foundation (M.S.), and the Naito Foundation Natural Science Scholarship (M.S.).","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"1523-7060","subitem_source_identifier_type":"ISSN"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"1598"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1601","bibliographicPageStart":"1598","bibliographicVolumeNumber":"18","bibliographic_titles":[{"bibliographic_title":"Organic Letters"},{"bibliographic_title":"Organic Letters"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://doi.org/10.1021/acs.orglett.6b00455"}],"subitem_relation_type":"isVersionOf"},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.orglett.6b00455","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"26986936","subitem_relation_type_select":"PMID"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"OrgLett_18_1598.pdf","filesize":[{"value":"644.7 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2007913/files/OrgLett_18_1598.pdf"},"version_id":"9b30eac1-cddc-4e54-911b-1fc7693b6f97"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"40589"},"item_title":"Spontaneous Oxygenation of Siloxy-N-silylketenimines to α-Ketoamides","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2007913","relation_version_is_last":true,"title":["Spontaneous Oxygenation of Siloxy-N-silylketenimines to α-Ketoamides"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T11:11:31.835701+00:00"}