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Organic−Inorganic Hybrid Nanocrystal-based Cryogels with Size- Controlled Mesopores and Macropores
https://hiroshima.repo.nii.ac.jp/records/2007636
https://hiroshima.repo.nii.ac.jp/records/2007636f8e9823d-73de-4849-8d33-88ef4991a12f
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
Langmuir_37_2884.pdf (809.1 KB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2023-03-18 | |||||||||||
| タイトル | ||||||||||||
| タイトル | Organic−Inorganic Hybrid Nanocrystal-based Cryogels with Size- Controlled Mesopores and Macropores | |||||||||||
| 言語 | en | |||||||||||
| 作成者 |
Tarutani, Naoki
× Tarutani, Naoki
× Hashimoto, Mana
× Ishigaki, Takamasa
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| アクセス権 | ||||||||||||
| アクセス権 | open access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | © 2021 American Chemical Society | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Langmuir, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.langmuir.0c03112 | |||||||||||
| 権利情報 | ||||||||||||
| 権利情報 | This is not the published version. Please cite only the published version. この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。 | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述 | Nanocrystal-based processing has attracted significant interest for the fabrication of highly functional materials with controlled crystallinity and fine porous structures. In this study, we focused on the template-free synthesis of nanocrystal-based materials with size-tailored pores using layered nickel hydroxide intercalated with acrylate anions. Polymerization of the acrylates encouraged interconnection of the nanocrystals and the formation of homogeneous gel networks. Cryogels after freeze-drying had pores with an average diameter from 4.8 nm (mesoscale) to 68.9 nm (macroscale). It was found that the surface characteristics of starting nanocrystals determined the phase separation tendency of interconnected species from the reaction media and resultant porous structures. We believe that the present study can enable the design of template-free nanocrystal-based porous materials. | |||||||||||
| 言語 | en | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述タイプ | Other | |||||||||||
| 内容記述 | The present work was partially supported by JSPS KAKENHI (JP20K15368), the MEXT Leading Initiative for Excellent Young Researchers, the Foundation for the Promotion of Ion Engineering, and the Izumi Science and Technology Foundation (2019-J-112). | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | American Chemical Society | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| 出版タイプ | ||||||||||||
| 出版タイプ | AO | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_b1a7d7d4d402bcce | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | 10.1021/acs.langmuir.0c03112 | |||||||||||
| 関連情報 | ||||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | https://doi.org/10.1021/acs.langmuir.0c03112 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 1520-5827 | |||||||||||
| 収録物識別子 | ||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||
| 収録物識別子 | AA10461730 | |||||||||||
| 開始ページ | ||||||||||||
| 開始ページ | 2884 | |||||||||||
| 書誌情報 |
Langmuir Langmuir 巻 37, 号 9, p. 2884-2890, 発行日 2021-02-12 |
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| 旧ID | 52860 | |||||||||||
