{"created":"2025-02-21T03:53:45.833592+00:00","id":2007496,"links":{},"metadata":{"_buckets":{"deposit":"688febc9-5041-4757-bd59-084ae2bbb89c"},"_deposit":{"created_by":41,"id":"2007496","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2007496"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02007496","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Infrared photodissociation spectroscopy of [Aniline-(Water)n]+ (n = 1-8): Structural change from branched and cyclic to proton-transferred forms","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Inokuchi, Yoshiya","creatorNameLang":"en"}],"familyNames":[{"familyName":"Inokuchi","familyNameLang":"en"}],"givenNames":[{"givenName":"Yoshiya","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ohashi, Kazuhiko","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ohashi","familyNameLang":"en"}],"givenNames":[{"givenName":"Kazuhiko","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Honkawa, Yoshiki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Honkawa","familyNameLang":"en"}],"givenNames":[{"givenName":"Yoshiki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yamamoto, Norifumi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Yamamoto","familyNameLang":"en"}],"givenNames":[{"givenName":"Norifumi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Sekiya, Hiroshi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Sekiya","familyNameLang":"en"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nishi, Nobuyuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Nishi","familyNameLang":"en"}],"givenNames":[{"givenName":"Nobuyuki","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2003 American Chemical Society"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Infrared photodissociation spectra of [aniline–(H2O)n]+ (n = 1–8) are measured in the 2700–3800 cm-1 region. The spectra are interpreted with the aid of density functional theory calculations. The n = 1 ion has an N–H•••O hydrogen bond. The spectrum of the n = 2 ion demonstrates a large perturbation to both of the NH oscillators, indicating the 1-1 structure where each NH bond is bound to a water molecule. For the n = 3 ion, the calculated spectrum of the 2-1 branched structure coincides well with the observed one. For the n = 4 ion, there exist three strong bands at 2960, 3100, and 3430 cm–1, and a very weak one at 3550 cm–1. The observed spectrum in the 3600–3800 cm–1 region is decomposed into four bands centered at 3640, 3698, 3710, and 3734 cm–1. The 2-2 branched isomer is responsible for all the features except the 3550 and 3710 cm–1 bands. These two bands are due to another isomer with a five-membered ring. An infrared band characteristic of the n = 5 ion appears at 3684 cm–1, which is not seen in the spectra of the n = 1–4 ions. This band is indicative of a ring structure and assigned to the free OH stretching vibration of the three-coordinated (double-acceptor–single-donor) H2O. The n = 5 ion has the five-membered ring structure with the fifth water molecule bound to the terminal (double-acceptor) H2O. The observed spectra of the n = 6–8 ions show features quite different from those of the n = 1–5 ions; a very strong and broad band emerges around 3400 cm–1, while no prominent bands appear below 3200 cm–1. It is suggested that the n = 6–8 ions have proton transferred structures.","subitem_description_language":"en"},{"subitem_description":"This is a preprint of an article published by American Chemical Society in Journal of Physical Chemistry A, 2003, available online: http://pubs.acs.org/doi/abs/10.1021/jp0225525","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"1089-5639","subitem_source_identifier_type":"ISSN"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"4230"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-05-29","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageEnd":"4237","bibliographicPageStart":"4230","bibliographicVolumeNumber":"107","bibliographic_titles":[{"bibliographic_title":"Journal of Physical Chemistry A "},{"bibliographic_title":"Journal of Physical Chemistry A "}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.1021/jp0225525","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/jp0225525","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"JPhysChemA_2003_107_4230.pdf","filesize":[{"value":"159.8 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2007496/files/JPhysChemA_2003_107_4230.pdf"},"version_id":"5f5179b9-c6e1-44a0-9e67-342f940d321b"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"14736"},"item_title":"Infrared photodissociation spectroscopy of [Aniline-(Water)n]+ (n = 1-8): Structural change from branched and cyclic to proton-transferred forms","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2007496","relation_version_is_last":true,"title":["Infrared photodissociation spectroscopy of [Aniline-(Water)n]+ (n = 1-8): Structural change from branched and cyclic to proton-transferred forms"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T10:05:37.107010+00:00"}