| Item type |
デフォルトアイテムタイプ_（フル）(1) |
| 公開日 |
2023-03-18 |
| タイトル |
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|
タイトル |
Charge Delocalization in Benzene-Naphthalene Hetero-Dimer Cation |
|
言語 |
en |
| 作成者 |
Matsumoto, Masaki
Inokuchi, Yoshiya
Ohashi, Kazuhiko
Nishi, Nobuyuki
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| アクセス権 |
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|
アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
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|
権利情報 |
Copyright (c) 1997 American Chemical Society |
| 主題 |
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主題Scheme |
NDC |
|
主題 |
430 |
| 内容記述 |
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|
内容記述 |
The electronic spectrum of the benzene–naphthalene hetero-dimer cation is measured in the 400–1200 nm region by the photodissociation spectroscopy. Most intense band at 580 nm is assigned to a local excitation (LE) band of the naphthalene cation chromophore. In addition to this band, an LE band of the benzene cation chromophore of the hetero-dimer is observed at nearly the same position (430 nm) as that of the benzene homo-dimer cation. The observation indicates that the positive charge stays on the benzene molecule in some probability, although the ionization potential of benzene is by 1.10 eV higher than that of naphthalene. The spectrum of the hetero-dimer cation also shows an intermolecular charge transfer (CT) band around 920 nm. On the basis of the position of the CT band as well as the intensity of the LE band relative to that of the homo-dimer, the probability of finding the charge on the benzene molecule is analyzed to be approximately 9 %. |
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言語 |
en |
| 内容記述 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
This work was supported in part by Grant-in-Aid for general research program (07454190) from the Ministry of Education, Science, Sports, and Culture of Japan. |
| 内容記述 |
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|
内容記述タイプ |
Other |
|
内容記述 |
This is a preprint of an article published by American Chemical Society in Journal of Physical Chemistry A, 1997, available online: http://pubs.acs.org/doi/abs/10.1021/jp9705939. |
| 出版者 |
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出版者 |
American Chemical Society |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AO |
|
出版タイプResource |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| 関連情報 |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
10.1021/jp9705939 |
| 関連情報 |
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|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
http://doi.org/10.1021/jp9705939 |
| 収録物識別子 |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
1089-5639 |
| 開始ページ |
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|
開始ページ |
4574 |
| 書誌情報 |
Journal of Physical Chemistry A
Journal of Physical Chemistry A
巻 101,
号 25,
p. 4574-4578,
発行日 1997-06-19
|
| 旧ID |
38235 |
JPhysChemA_1997_101_4574.pdf (254.8 KB)
