{"created":"2025-02-21T03:52:21.055419+00:00","id":2007450,"links":{},"metadata":{"_buckets":{"deposit":"92ecc1cf-fbbc-4d20-a003-8647e8654049"},"_deposit":{"created_by":41,"id":"2007450","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2007450"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02007450","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Palladium-catalyzed synthesis of poly(bromoalkoxy- and bromoalkanoyloxy-methylsiloxane)s from poly(hydromethylsiloxane)s","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohshita, Joji","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ohshita","familyNameLang":"en"}],"givenNames":[{"givenName":"Joji","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Inata, Ko","creatorNameLang":"en"}],"familyNames":[{"familyName":"Inata","familyNameLang":"en"}],"givenNames":[{"givenName":"Ko","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Izumi, Yuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Izumi","familyNameLang":"en"}],"givenNames":[{"givenName":"Yuki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kunai, Atsutaka","creatorNameLang":"en"}],"familyNames":[{"familyName":"Kunai","familyNameLang":"en"}],"givenNames":[{"givenName":"Atsutaka","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2007 Elsevier B.V."}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"Polysiloxane","subitem_subject_scheme":"Other"},{"subitem_subject":"Palladium catalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"Cyclic ether","subitem_subject_scheme":"Other"},{"subitem_subject":"Lactone","subitem_subject_scheme":"Other"},{"subitem_subject":"Bromosilane","subitem_subject_scheme":"Other"},{"subitem_subject":"Ring opening","subitem_subject_scheme":"Other"},{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Palladium-catalyzed synthesis of poly(bromoalkoxymethyl- and bromoalkanoyloxy-methylsiloxane)s from poly(hydromethylsiloxane)s was studied. Treatment of poly(hydromethylsiloxane)s with mixtures of allyl bromide and cyclic ethers in the presence of a catalytic amount of PdCl2 gave the corresponding poly[(bromoalkoxy)methylsiloxane]s in good yield. A similar reaction with γ-butyrolactone produced poly[(bromobutanoyloxy)methylsiloxane], although the polymer was highly moisture-sensitive and could not be separated from the reaction mixture. Transformation of the bromoalkoxy unit in the resulting siloxane polymer into an aminoalkoxy group was also examined.","subitem_description_language":"en"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Elsevier Science B.V."}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"0022-328X","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA00704122","subitem_source_identifier_type":"NCID"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"3526"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007-07-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"15","bibliographicPageEnd":"3531","bibliographicPageStart":"3526","bibliographicVolumeNumber":"692","bibliographic_titles":[{"bibliographic_title":"Journal of Organometallic Chemistry"},{"bibliographic_title":"Journal of Organometallic Chemistry"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jorganchem.2007.04.038","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1016/j.jorganchem.2007.04.038","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"JOrganoChem_692-15_3526.pdf","filesize":[{"value":"250.1 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2007450/files/JOrganoChem_692-15_3526.pdf"},"version_id":"f8961596-1316-431f-b8dd-27ab4adb01c2"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"21450"},"item_title":"Palladium-catalyzed synthesis of poly(bromoalkoxy- and bromoalkanoyloxy-methylsiloxane)s from poly(hydromethylsiloxane)s","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2007450","relation_version_is_last":true,"title":["Palladium-catalyzed synthesis of poly(bromoalkoxy- and bromoalkanoyloxy-methylsiloxane)s from poly(hydromethylsiloxane)s"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T09:58:24.676942+00:00"}