| Item type |
デフォルトアイテムタイプ_(フル)(1) |
| 公開日 |
2023-03-18 |
| タイトル |
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|
タイトル |
X-ray diffraction measurements for expanded fluid-Se using synchrotron radiation |
|
言語 |
en |
| 作成者 |
Inui, Masanori
Tamura, Kozaburo
Oh'ishi, Yasufumi
Nakaso, Ichiro
Funakoshi, Ken-ichi
Utsumi, Wataru
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| アクセス権 |
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|
アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利情報 |
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|
権利情報 |
Copyright (c) 1999 Elsevier Science B.V. All rights reserved. |
| 主題 |
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主題Scheme |
NDC |
|
主題 |
420 |
| 内容記述 |
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内容記述 |
X-ray diffraction measurements at temperatures up to 1500C and pressures up to 843 bar have been carried out using synchrotron radiation at SPring-8 to investigate structural change in the semiconductor-to-metal transition in expanded fluid-Se. The signal-to-noise ratio in the intensity spectra was better than the previous one using in-house X-ray source. It is found important to estimate the background from a sapphire cell to deduce a structure factor of fluid Se with greater accuracy from the spectra. The preservation of the twofold coordinated chain structure and the contraction of the covalent bond are reconfirmed in the transition. When metallic properties were increased, the first peak in the pair distribution function became asymmetric towards larger distance and the first minimum became larger. These results may imply the modification on the chain structure in the transition. |
|
言語 |
en |
| 出版者 |
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出版者 |
Elsevier Science B.V. |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AO |
|
出版タイプResource |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
| 関連情報 |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
10.1016/S0022-3093(99)00283-5 |
| 関連情報 |
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|
識別子タイプ |
DOI |
|
|
関連識別子 |
http://dx.doi.org/10.1016/S0022-3093(99)00283-5 |
| 収録物識別子 |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0022-3093 |
| 収録物識別子 |
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|
収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA00703560 |
| 開始ページ |
|
|
開始ページ |
519 |
| 書誌情報 |
Journal of Non-Crystalline Solids
Journal of Non-Crystalline Solids
巻 250-252,
号 2,
p. 519-524,
発行日 1999-08-01
|
| 旧ID |
26516 |