{"created":"2025-02-21T03:46:31.729385+00:00","id":2007258,"links":{},"metadata":{"_buckets":{"deposit":"cf96f1a8-9f17-4997-a670-2e73a7c94d08"},"_deposit":{"created_by":41,"id":"2007258","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2007258"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02007258","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"IR induced cis↔trans isomerization of 2-naphthol : Catalytic role of hydrogen-bond in the photoinduced isomerization","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ebata, Takayuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ebata","familyNameLang":"en"}],"givenNames":[{"givenName":"Takayuki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kouyama, Kyouko","creatorNameLang":"en"}],"familyNames":[{"familyName":"Kouyama","familyNameLang":"en"}],"givenNames":[{"givenName":"Kyouko","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Mikami, Naohiko","creatorNameLang":"en"}],"familyNames":[{"familyName":"Mikami","familyNameLang":"en"}],"givenNames":[{"givenName":"Naohiko","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2003 American Institute of Physics."}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"An infrared laser induced cis↔trans isomerization has been investigated for 2-naphthol and its hydrogen(H)-bonded cluster with NH3 in the S1 electronic state by UV–IR double resonance excitation in a supersonic jet. A specific isomer was pumped to a X–H (X=O, C or N) stretching vibration in S1 by a sequential UV–IR two-photon excitation, and the resultant product species were analyzed by dispersing their fluorescence. It was found that the IR excitation induces the isomerization for the H-bonded cluster with the excitation less than 3000 cm-1, while no isomerization was found to occur for bare 2NpOH even with an input energy of 3610 cm-1. The substantial reduction of the isomerization barrier height represents evidence of the catalytic nature of H-bonding in the conformational isomerization. It was also found that the isomerization efficiency is very high at low IR frequency and exhibits a marked IR frequency dependence.","subitem_description_language":"en"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Institute of Physics"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"0021-9606","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA00694991","subitem_source_identifier_type":"NCID"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"2947"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-08-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"2950","bibliographicPageStart":"2947","bibliographicVolumeNumber":"119","bibliographic_titles":[{"bibliographic_title":"Journal of Chemical Physics"},{"bibliographic_title":"Journal of Chemical Physics"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1063/1.1596831","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1063/1.1596831","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"JChemPhys_119_2947.pdf","filesize":[{"value":"85.6 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2007258/files/JChemPhys_119_2947.pdf"},"version_id":"132db0e3-f0a2-418e-876e-01c88caaf3f0"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"18819"},"item_title":"IR induced cis↔trans isomerization of 2-naphthol : Catalytic role of hydrogen-bond in the photoinduced isomerization","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2007258","relation_version_is_last":true,"title":["IR induced cis↔trans isomerization of 2-naphthol : Catalytic role of hydrogen-bond in the photoinduced isomerization"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T09:34:45.514032+00:00"}