{"created":"2025-02-21T03:45:08.992154+00:00","id":2007214,"links":{},"metadata":{"_buckets":{"deposit":"7b2bd62f-f655-42c4-a7a7-88382a084015"},"_deposit":{"created_by":41,"id":"2007214","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2007214"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02007214","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Magnetic diagnostics using the third-harmonic magnetic response for a molecule-based magnet networked by a single chiral ligand","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Mito, Masaki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Mito","familyNameLang":"en"}],"givenNames":[{"givenName":"Masaki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Iriguchi, K.","creatorNameLang":"en"}],"familyNames":[{"familyName":"Iriguchi","familyNameLang":"en"}],"givenNames":[{"givenName":"K.","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Deguchi, Hiroyuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Deguchi","familyNameLang":"en"}],"givenNames":[{"givenName":"Hiroyuki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kishine, Jun-Ichiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Kishine","familyNameLang":"en"}],"givenNames":[{"givenName":"Jun-Ichiro","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yoshida, Yusuke","creatorNameLang":"en"}],"familyNames":[{"familyName":"Yoshida","familyNameLang":"en"}],"givenNames":[{"givenName":"Yusuke","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Inoue, Katsuya","creatorNameLang":"en"}],"familyNames":[{"familyName":"Inoue","familyNameLang":"en"}],"givenNames":[{"givenName":"Katsuya","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"(c) 2012 American Institute of Physics"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"We investigated complex magnetic domain formation on a chiral molecule-based magnet, [Cr(CN)6][Mn(R)-pnH(H2O)](H2O) (termed as R-GN), whose two-dimensional molecular network was constructed with the help of a single-handed chiral ligand ((R)-pn). There, the first- and third-harmonic magnetic responses (M1ω and M3ω) against the ac magnetic field were observed, and magnetic hysteresis in ac field of a few Oe was discussed in terms of Rayleigh loop. The diagnostics of this magnetic hysteresis clarified the complex process of magnetic domain formation against a change in temperature. For R-GN, it was reported that a giant M3ω (termed #4 in this paper) appeared just above the so-called “magnetic ordering temperature (TC).\" In the present study, three M3ω responses (#1-3) were newly observed on the lower-temperature side of #4, and the ac field dependencies for all of #1-#4 were investigated. #1 also accompanied the giant M3ω, which suggests that a significant degree of magnetic fluctuation surviving below TC. This glassy behavior below TC is an attractive new phenomenon in molecule-based magnets with a single-handed chiral ligand. #2 and #3 exhibited magnetic ordering and the formation of a small magnetic domain, respectively. The M3ω responses of #1-3 were suppressed with increasing the amplitude of ac field, and the corresponding magnetic hysteresis was a normal Rayleigh loop accompanying the out-of-phase of the M1ω response. The M3ω response of #4 without the out-of-phase of M1ω was, however, enhanced with increasing the amplitude of ac field, and #4 represented a large magnetic hysteresis in the paramagnetic region, intrinsically different from those of #1-#3.","subitem_description_language":"en"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Institute of Physics"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"0021-8979","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA00693547","subitem_source_identifier_type":"NCID"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"103914"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageStart":"103914","bibliographicVolumeNumber":"111","bibliographic_titles":[{"bibliographic_title":"Journal of Applied Physics"},{"bibliographic_title":"Journal of Applied Physics"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1063/1.4721806","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1063/1.4721806","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"JApplPhys_111_103914.pdf","filesize":[{"value":"1.1 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2007214/files/JApplPhys_111_103914.pdf"},"version_id":"c7fe125f-a1a4-495f-bf18-ccba958d0545"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"33950"},"item_title":"Magnetic diagnostics using the third-harmonic magnetic response for a molecule-based magnet networked by a single chiral ligand","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2007214","relation_version_is_last":true,"title":["Magnetic diagnostics using the third-harmonic magnetic response for a molecule-based magnet networked by a single chiral ligand"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T09:27:45.239949+00:00"}