{"created":"2025-02-21T03:40:24.586209+00:00","id":2007070,"links":{},"metadata":{"_buckets":{"deposit":"8ae56406-2f59-457d-b5f0-b947b764d74b"},"_deposit":{"created_by":41,"id":"2007070","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2007070"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02007070","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"UV and IR Spectroscopy of Cryogenically Cooled, Lanthanide-Containing Ions in the Gas Phase","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Inokuchi, Yoshiya","creatorNameLang":"en"}],"familyNames":[{"familyName":"Inokuchi","familyNameLang":"en"}],"givenNames":[{"givenName":"Yoshiya","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kaneko, Masashi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Kaneko","familyNameLang":"en"}],"givenNames":[{"givenName":"Masashi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Honda, Takumi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Honda","familyNameLang":"en"}],"givenNames":[{"givenName":"Takumi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nakashima, Satoru","creatorNameLang":"en"}],"familyNames":[{"familyName":"Nakashima","familyNameLang":"en"}],"givenNames":[{"givenName":"Satoru","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ebata, Takayuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ebata","familyNameLang":"en"}],"givenNames":[{"givenName":"Takayuki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Rizzo, Thomas R.","creatorNameLang":"en"}],"familyNames":[{"familyName":"Rizzo","familyNameLang":"en"}],"givenNames":[{"givenName":"Thomas R.","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2016 American Chemical Society"},{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Inorganic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.6b02134"},{"subitem_rights":"This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"lanthanide","subitem_subject_scheme":"Other"},{"subitem_subject":"ultraviolet spectroscopy","subitem_subject_scheme":"Other"},{"subitem_subject":"conformation","subitem_subject_scheme":"Other"},{"subitem_subject":"cold ion trap","subitem_subject_scheme":"Other"},{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"We measure UV and IR spectra in the gas phase for EuOH+, EuCl+, and TbO+ ions, which are produced by an electrospray ionization source and cooled to ~10 K in a cold, 22-pole ion trap. The UV photodissociation (UVPD) spectra of these ions show a number of sharp, well-resolved bands in the 30000–38000 cm–1 region, although a definite assignment of the spectra is difficult because of a high degree of congestion. We also measure an IR spectrum of the EuOH+ ion in the 3500–3800 cm–1 region by IR-UV double resonance spectroscopy, which reveals an OH stretching band at 3732 cm–1. We perform density functional theory (DFT) and time-dependent DFT (TD-DFT) calculations of these ions in order to examine the nature of the transitions. The DFT results indicate that the states of highest spin multiplicity (octet for EuOH+ and EuCl+, and septet for TbO+) is substantially more stable than other states of lower spin multiplicity. The TD-DFT calculations suggest that the UV absorption of the EuOH+ and EuCl+ ions arises from Eu(4f)→Eu(5d, 6p) transitions, whereas the electronic transitions of the TbO+ ion are mainly due to the electron promotion of O(2p)→Tb(4f, 6s). The UVPD results of the lanthanide-containing ions in this study suggest the possibility of using lanthanide ions as “conformation reporters\" for the gas-phase spectroscopy for large molecules.","subitem_description_language":"en"},{"subitem_description":"This work was partly supported by JSPS KAKENHI Grant Number 16H04098 and by the Swiss National Science Foundation under grant number 200020_152804.","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"0020-1669","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1520-510X","subitem_source_identifier_type":"ISSN"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"277"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-12-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"281","bibliographicPageStart":"277","bibliographicVolumeNumber":"56","bibliographic_titles":[{"bibliographic_title":"Inorganic Chemistry"},{"bibliographic_title":"Inorganic Chemistry"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.inorgchem.6b02134","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"27997155","subitem_relation_type_select":"PMID"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"InorgChem_2017_56_277.pdf","filesize":[{"value":"964.5 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2007070/files/InorgChem_2017_56_277.pdf"},"version_id":"1df2efe3-4eb1-4fa6-832f-d77303226531"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"45813"},"item_title":"UV and IR Spectroscopy of Cryogenically Cooled, Lanthanide-Containing Ions in the Gas Phase","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2007070","relation_version_is_last":true,"title":["UV and IR Spectroscopy of Cryogenically Cooled, Lanthanide-Containing Ions in the Gas Phase"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T09:04:12.225180+00:00"}