{"created":"2025-02-21T03:30:06.040520+00:00","id":2006723,"links":{},"metadata":{"_buckets":{"deposit":"ae3a6df2-5e5f-437c-a4e3-5b6d438ce7a3"},"_deposit":{"created_by":41,"id":"2006723","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2006723"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02006723","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Preparation and isolation of mono-Nb substituted Keggin-type phosphomolybdic acid and its application as an oxidation catalyst for isobutylaldehyde and Wacker-type oxidation","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Matono, Takashi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Matono","familyNameLang":"en"}],"givenNames":[{"givenName":"Takashi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ueno, Shinsuke","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ueno","familyNameLang":"en"}],"givenNames":[{"givenName":"Shinsuke","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Kato, Yuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Kato","familyNameLang":"en"}],"givenNames":[{"givenName":"Yuki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Umehara, Naoya","creatorNameLang":"en"}],"familyNames":[{"familyName":"Umehara","familyNameLang":"en"}],"givenNames":[{"givenName":"Naoya","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Lang, Zhongling","creatorNameLang":"en"}],"familyNames":[{"familyName":"Lang","familyNameLang":"en"}],"givenNames":[{"givenName":"Zhongling","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Li, Yangguang","creatorNameLang":"en"}],"familyNames":[{"familyName":"Li","familyNameLang":"en"}],"givenNames":[{"givenName":"Yangguang","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ninomiya, Wataru ","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ninomiya","familyNameLang":"en"}],"givenNames":[{"givenName":"Wataru ","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Elhallal, Maher","creatorNameLang":"en"}],"familyNames":[{"familyName":"Elhallal","familyNameLang":"en"}],"givenNames":[{"givenName":"Maher","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Gonzales-Yañez, Edgar Osiris","creatorNameLang":"en"}],"familyNames":[{"familyName":"Gonzales-Yañez","familyNameLang":"en"}],"givenNames":[{"givenName":"Edgar Osiris","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Capron, Mickael","creatorNameLang":"en"}],"familyNames":[{"familyName":"Capron","familyNameLang":"en"}],"givenNames":[{"givenName":"Mickael","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ishikawa, Satoshi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ishikawa","familyNameLang":"en"}],"givenNames":[{"givenName":"Satoshi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ueda, Wataru","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ueda","familyNameLang":"en"}],"givenNames":[{"givenName":"Wataru","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Sano, Tsuneji","creatorNameLang":"en"}],"familyNames":[{"familyName":"Sano","familyNameLang":"en"}],"givenNames":[{"givenName":"Tsuneji","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Sadakane, Masahiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Sadakane","familyNameLang":"en"}],"givenNames":[{"givenName":"Masahiro","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"This is an accepted manuscript of the paper which has been published in final form at https://doi.org/10.1039/D3DT02451B","subitem_rights_language":"en"},{"subitem_rights":"This is not the published version. Please cite only the published version. ","subitem_rights_language":"en"},{"subitem_rights":"この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。","subitem_rights_language":"ja"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"The potassium and proton mixed salt of mono-Nb substituted Keggin-type phosphomolybdate, KH3[PMo11NbO40], was isolated in a pure form by reacting Keggin-type phosphomolybdic acid (H3[PMo12O40]) and potassium hexaniobate (K8Nb6O19) in water, followed by freeze-drying. The all protonic form, H4[PMo11NbO40], was isolated via proton exchange with H-resin and subsequent freeze-drying. The most crucial factor to isolate KH3[PMo11NbO40] and H4[PMo11NbO40] in pure forms is the evaporation of water using the freeze-drying method. Using a similar procedure, the potassium salt of the di-Nb substituted compound K5[PMo10Nb2O40] was isolated. H4[PMo11NbO40] exhibited high catalytic activity for oxidizing isobutylaldehyde to methacrolein and moderate catalytic activity for the Wacker-type oxidation of allyl phenyl ether when combined with Pd(OAc)2.","subitem_description_language":"en"},{"subitem_description":"This work was supported by the Grant-in-Aid for Transformative Research Area (A) “Supra-ceramics\" (JSPS KAKENHI Grant Number JP22H05144), JSPS Core-to-Core Program, International Associated Laboratory (LIA) “Nano oxide-based catalysts for biomass valorization (NANOXCAT)\", and International Network on Polyoxometalate Science at Hiroshima University. ","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry","subitem_publisher_language":"en"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186901218":{"attribute_name":"Funding Reference","attribute_value_mlt":[{"subitem_award_numbers":{"subitem_award_number":"JP22H05144","subitem_award_uri":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PLANNED-22H05144/"},"subitem_award_titles":[{"subitem_award_title":"超セラミックスの次元・形態制御","subitem_award_title_language":"ja"}],"subitem_funder_names":[{"subitem_funder_name":"日本学術振興会","subitem_funder_name_language":"ja"}]},{"subitem_award_titles":[{"subitem_award_title":"Controls of Structural dimensionality and Crystal morphology of Supra-ceramics","subitem_award_title_language":"en"}],"subitem_funder_names":[{"subitem_funder_name":"Japan Society for the Promotion of Science","subitem_funder_name_language":"en"}]}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"18168"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-11-02","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"18176","bibliographicPageStart":"18168","bibliographicVolumeNumber":"52","bibliographic_titles":[{"bibliographic_title":"Dalton Transactions","bibliographic_titleLang":"en"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/D3DT02451B","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2025-01-30"}],"displaytype":"simple","filename":"DT_48_18168.pdf","filesize":[{"value":"1.2 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2006723/files/DT_48_18168.pdf"},"version_id":"20636eef-be6a-4f47-97d3-e989b6460c41"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"56190"},"item_title":"Preparation and isolation of mono-Nb substituted Keggin-type phosphomolybdic acid and its application as an oxidation catalyst for isobutylaldehyde and Wacker-type oxidation","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2025-01-30"},"publish_date":"2025-01-30","publish_status":"0","recid":"2006723","relation_version_is_last":true,"title":["Preparation and isolation of mono-Nb substituted Keggin-type phosphomolybdic acid and its application as an oxidation catalyst for isobutylaldehyde and Wacker-type oxidation"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T08:17:37.472858+00:00"}