{"created":"2025-02-21T03:27:34.531279+00:00","id":2006644,"links":{},"metadata":{"_buckets":{"deposit":"4630b286-b5b0-4e51-b201-471479b35580"},"_deposit":{"created_by":41,"id":"2006644","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2006644"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02006644","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Slow Intermolecular Complexation–Decomplexation Exchanges of Cyclodextrins in Fullerene and Its Derivative Complexes","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ikeda, Atsushi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ikeda","familyNameLang":"en"}],"givenNames":[{"givenName":"Atsushi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Mae, Tomoya","creatorNameLang":"en"}],"familyNames":[{"familyName":"Mae","familyNameLang":"en"}],"givenNames":[{"givenName":"Tomoya","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Sugikawa, Kouta","creatorNameLang":"en"}],"familyNames":[{"familyName":"Sugikawa","familyNameLang":"en"}],"givenNames":[{"givenName":"Kouta","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Komaguchi, Kenji","creatorNameLang":"en"}],"familyNames":[{"familyName":"Komaguchi","familyNameLang":"en"}],"givenNames":[{"givenName":"Kenji","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Konishi, Toshifumi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Konishi","familyNameLang":"en"}],"givenNames":[{"givenName":"Toshifumi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Hirao, Takehiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Hirao","familyNameLang":"en"}],"givenNames":[{"givenName":"Takehiro","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Haino, Takeharu","creatorNameLang":"en"}],"familyNames":[{"familyName":"Haino","familyNameLang":"en"}],"givenNames":[{"givenName":"Takeharu","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim"},{"subitem_rights":"This is the accepted version of the following article: A. Ikeda, T. Mae, K. Sugikawa, K. Komaguchi, T. Konishi, T. Hirao, and T. Haino, Slow Intermolecular Complexation–Decomplexation Exchanges of Cyclodextrins in Fullerene and Its Derivative Complexes, ChemistrySelect, 2, 11322–11327, 2017, which has been published in final form at http://doi.org/10.1002/slct.201702319. This article may be used for non-commercial purposes in accordance with Wiley Self-Archiving Policy."},{"subitem_rights":"This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"cyclodextrins","subitem_subject_scheme":"Other"},{"subitem_subject":"fullerenes","subitem_subject_scheme":"Other"},{"subitem_subject":"host-guest systems","subitem_subject_scheme":"Other"},{"subitem_subject":"pseudorotaxanes","subitem_subject_scheme":"Other"},{"subitem_subject":"NMR spectroscopy","subitem_subject_scheme":"Other"},{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Fullerenes (C60 and C70) and several functionalized C60 derivatives can be encapsulated in two γ-cyclodextrins (γ-CDxs). Although intermolecular complexation–decomplexation exchange of γ-CDx is known to be very slow, the exchange rates have yet to be quantitatively measured. Herein, we determined that the pseudo-firstorder association and dissociation rate constants for the γ-CDx2•C70 complex were 4.3 and 0.6 s−1 at 23℃, respectively. In contrast, the intermolecular exchange rates for the γ-CDx2•C60 and C60 derivative complexes were slower than the time scale of exchange spectroscopy NMR experiments and the exchange rate constants were in the order of 10−4 s−1. Furthermore, a γ-CDx2•C60 derivative complex was shown to have different intermolecular exchange rates for the two γ-CDxs depending on steric hindrance from the substituent on the C60 derivative.","subitem_description_language":"en"},{"subitem_description":"This work was supported by JSPS KAKENHI Grant-in-Aid for Scientific Research (B) (Grant No. JP16H04133) and Grant-in-Aid for Challenging Exploratory Research (Grant No. JP16K13982).","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Wiley-VCH"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"2365-6549","subitem_source_identifier_type":"ISSN"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"11322"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-12-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"34","bibliographicPageEnd":"11327","bibliographicPageStart":"11322","bibliographicVolumeNumber":"2","bibliographic_titles":[{"bibliographic_title":"ChemistrySelect"},{"bibliographic_title":"ChemistrySelect"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/slct.201702319","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-12-01"}],"displaytype":"simple","fileDate":[{"fileDateType":"Available","fileDateValue":"2018-12-01"}],"filename":"ChemSelect_2-34_11322.pdf","filesize":[{"value":"1.1 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2006644/files/ChemSelect_2-34_11322.pdf"},"version_id":"168ac352-4caa-415f-8c4b-80b5d9f34408"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"46211"},"item_1732772494514":{"attribute_name":"備考","attribute_value":"Post-print version/PDF may be used in an institutional repository after an embargo period of 12 months."},"item_title":"Slow Intermolecular Complexation–Decomplexation Exchanges of Cyclodextrins in Fullerene and Its Derivative Complexes","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2006644","relation_version_is_last":true,"title":["Slow Intermolecular Complexation–Decomplexation Exchanges of Cyclodextrins in Fullerene and Its Derivative Complexes"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T08:05:16.337274+00:00"}