{"created":"2025-02-21T03:27:27.399282+00:00","id":2006640,"links":{},"metadata":{"_buckets":{"deposit":"9b043861-b421-4476-80e3-192e6ab82408"},"_deposit":{"created_by":41,"id":"2006640","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2006640"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02006640","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Photophysical properties of donor–acceptor antiaromatic organoboron compounds based on dithienodiborinines","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Adachi, Yohei","creatorNameLang":"en"}],"familyNames":[{"familyName":"Adachi","familyNameLang":"en"}],"givenNames":[{"givenName":"Yohei","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Hasegawa, Takumi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Hasegawa","familyNameLang":"en"}],"givenNames":[{"givenName":"Takumi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ohshita, Joji","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ohshita","familyNameLang":"en"}],"givenNames":[{"givenName":"Joji","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"embargoed access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_f1cf"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"This is a pre-copyedited, author-produced version of an article accepted for publication in Chemistry Letters following peer review. The version of record Volume 53, Issue 8, August 2024, upae161 is available online at: https://doi.org/10.1093/chemle/upae161.","subitem_rights_language":"en"},{"subitem_rights":"This is not the published version. Please cite only the published version.","subitem_rights_language":"en"},{"subitem_rights":"この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。","subitem_rights_language":"ja"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"antiaromatic","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"boron","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"diborinine","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Boron-containing antiaromatics, such as diborinines and boroles, have sparked interest in materials chemists owing to their exciting optical properties and high Lewis acidity. In this study, we synthesized donor–acceptor (D–A) type diborinines fused with thiophene rings by introducing electron-donating amino-substituted aryl groups onto boron and elucidated their properties. The D–A type dithienodiborinines exhibited long-wavelength absorption arising from their D–A interactions and antiaromaticity. In addition, their fluorescence intensity increased under oxygen-free conditions, indicating thermally activated delayed fluorescence.","subitem_description_language":"en"},{"subitem_description":"This work was supported by the Furukawa Foundation for the Promotion of Technology.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Oxford","subitem_publisher_language":"en"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"upae161"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2024-08-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageStart":"upae161","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"Chemistry Letters","bibliographic_titleLang":"en"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1093/chemle/upae161","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2025-08-20"}],"displaytype":"simple","fileDate":[{"fileDateType":"Available","fileDateValue":"2025-08-20"}],"filename":"ChemLett_53_upae161.pdf","filesize":[{"value":"642.3 KB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2006640/files/ChemLett_53_upae161.pdf"},"version_id":"198196f8-64c1-4828-b98b-3af32d3768c4"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"55911"},"item_1732772494514":{"attribute_name":"備考","attribute_value":"The full-text file will be made open to the public on 20 August 2025 in accordance with publisher's 'Terms and Conditions for Self-Archiving'"},"item_title":"Photophysical properties of donor–acceptor antiaromatic organoboron compounds based on dithienodiborinines","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-12-27"},"publish_date":"2024-12-27","publish_status":"0","recid":"2006640","relation_version_is_last":true,"title":["Photophysical properties of donor–acceptor antiaromatic organoboron compounds based on dithienodiborinines"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T08:04:53.054861+00:00"}