{"created":"2025-02-21T03:14:47.550414+00:00","id":2006230,"links":{},"metadata":{"_buckets":{"deposit":"951d38f0-1cb4-43da-98a0-53e06e34d6e8"},"_deposit":{"created_by":41,"id":"2006230","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2006230"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02006230","sets":["1730444907710"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Microhydration Effects on the Intermediates of the (I- + CH3I) SN2 Reaction <Solvent Effect>","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Doi, Keisuke","creatorNameLang":"en"}],"familyNames":[{"familyName":"Doi","familyNameLang":"en"}],"givenNames":[{"givenName":"Keisuke","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Togano, Eijiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Togano","familyNameLang":"en"}],"givenNames":[{"givenName":"Eijiro","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Xantheas, Sotiris S.","creatorNameLang":"en"}],"familyNames":[{"familyName":"Xantheas","familyNameLang":"en"}],"givenNames":[{"givenName":"Sotiris S.","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nakanishi, Ryuzo","creatorNameLang":"en"}],"familyNames":[{"familyName":"Nakanishi","familyNameLang":"en"}],"givenNames":[{"givenName":"Ryuzo","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nagata, Takashi","creatorNameLang":"en"}],"familyNames":[{"familyName":"Nagata","familyNameLang":"en"}],"givenNames":[{"givenName":"Takashi","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ebata, Takayuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"Ebata","familyNameLang":"en"}],"givenNames":[{"givenName":"Takayuki","givenNameLang":"en"}]},{"creatorNames":[{"creatorName":"Inokuchi, Yoshiya","creatorNameLang":"en"}],"familyNames":[{"familyName":"Inokuchi","familyNameLang":"en"}],"givenNames":[{"givenName":"Yoshiya","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"halides","subitem_subject_scheme":"Other"},{"subitem_subject":"IR spectroscopy","subitem_subject_scheme":"Other"},{"subitem_subject":"SN2 reactions","subitem_subject_scheme":"Other"},{"subitem_subject":"solvent effects","subitem_subject_scheme":"Other"},{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Hydrated I-(CH3I) complexes, I-(CH3I)(H2O)1-3, are investigated by IR photodissociation spectroscopy for examining the stable structures of the intermediates of the (I- + CH3I → ICH3 + I-) SN2 reaction under hydrated conditions. The structures and the energetics of the complexes suggest that just one or two H2O molecules will effectively inhibit this SN2 reaction.","subitem_description_language":"en"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Wiley-VCH Verlag GmbH"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_source_identifier":"1521-3773","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA11614189","subitem_source_identifier_type":"NCID"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"4380"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-01-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"16","bibliographicPageEnd":"4383","bibliographicPageStart":"4380","bibliographicVolumeNumber":"52","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie International Edition"},{"bibliographic_title":"Angewandte Chemie International Edition"}]}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://doi.org/10.1002/anie.201207697"}],"subitem_relation_type":"isVersionOf"},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/anie.201207697","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"AngewChemIntEd_2013_52_4380.pdf","filesize":[{"value":"2.8 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2006230/files/AngewChemIntEd_2013_52_4380.pdf"},"version_id":"ba8d5da7-dec9-44cc-bc85-28bee9ca2c25"}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"37652"},"item_title":"Microhydration Effects on the Intermediates of the (I- + CH3I) SN2 Reaction <Solvent Effect>","item_type_id":"40003","owner":"41","path":["1730444907710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2006230","relation_version_is_last":true,"title":["Microhydration Effects on the Intermediates of the (I- + CH3I) SN2 Reaction <Solvent Effect>"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T07:01:58.741008+00:00"}