WEKO3
アイテム
Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments
https://hiroshima.repo.nii.ac.jp/records/2006133
https://hiroshima.repo.nii.ac.jp/records/200613311b4d534-f10d-40fc-a345-e681d0713485
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ACSCatal_6_1799.pdf (1.1 MB)
|
| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||
|---|---|---|---|---|---|---|---|---|
| 公開日 | 2023-03-18 | |||||||
| タイトル | ||||||||
| タイトル | Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments | |||||||
| 言語 | en | |||||||
| 作成者 |
Yoshida, Hiroto
× Yoshida, Hiroto
|
|||||||
| アクセス権 | ||||||||
| アクセス権 | open access | |||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||
| 権利情報 | ||||||||
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.5b02973. | |||||||
| 権利情報 | ||||||||
| 権利情報 | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。 | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | alkenylborane synthesis | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | alkynes | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | base metal catalysis | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | boron | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | coinage metal catalysis | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | regioselectivity | |||||||
| 主題 | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | stereoselectivity | |||||||
| 内容記述 | ||||||||
| 内容記述 | Alkenylboranes have been vital reagents in modern synthetic organic chemistry, whose carbon–boron bond is transformable into a carbon–carbon bond stereoretentively to give such invaluable mutisubstituted alkenes as natural products, biologically active molecules and functional materials. Introduction of a boryl moiety across a carbon–carbon triple bond of alkynes (borylation of alkynes) is one of the most direct and potent methods for synthesizing alkenylboranes, and this field has thus far experienced remarkable progress mainly with group 10 transition metal catalysts (Ni, Pd, Pt), which enables highly functionalized alkenylboranes to be constructed stereoselectively. On the other hand, much attention has recently been focused on appealing catalysis of base (Fe, Co) and coinage (Cu, Ag, Au) metals toward the borylation of alkynes, which is summarized in this perspective. | |||||||
| 言語 | en | |||||||
| 出版者 | ||||||||
| 出版者 | American Chemical Society | |||||||
| 言語 | ||||||||
| 言語 | eng | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
| 資源タイプ | journal article | |||||||
| 出版タイプ | ||||||||
| 出版タイプ | AO | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_b1a7d7d4d402bcce | |||||||
| 関連情報 | ||||||||
| 識別子タイプ | DOI | |||||||
| 関連識別子 | 10.1021/acscatal.5b02973 | |||||||
| 関連情報 | ||||||||
| 識別子タイプ | DOI | |||||||
| 関連識別子 | https://doi.org/10.1021/acscatal.5b02973 | |||||||
| 収録物識別子 | ||||||||
| 収録物識別子タイプ | ISSN | |||||||
| 収録物識別子 | 2155-5435 | |||||||
| 開始ページ | ||||||||
| 開始ページ | 1799 | |||||||
| 書誌情報 |
ACS Catalysis ACS Catalysis 巻 6, 号 3, p. 1799-1811, 発行日 2016-02-03 |
|||||||
| 旧ID | 48768 | |||||||
