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Asymmetric Induction in Darzens Condensation  　Introduction / p19  　Results and Discussion / p22  　Experimental Section / p38  　Supplementary Material / p54  　References / p67  Chapter2. Stereoselectivity in the Formation of 2,5-Disubstituted Tetrahydropyran by Intramolecular Hetero-Michael Addition  　Introduction / p71  　Results and Discussion / p74  　Experimental Section / p94  　Supplementary Material / p125  　References / p148  List of Publications / p152","subitem_description_type":"TableOfContents"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186819068":{"attribute_name":"Identifier Registration","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.11501/3147630","subitem_identifier_reg_type":"JaLC"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"1"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicPageStart":"1"}]},"item_1617187087799":{"attribute_name":"Dissertation Number","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第1768号"}]},"item_1617187112279":{"attribute_name":"Degree Name","attribute_value_mlt":[{"subitem_degreename":"博士(理学)","subitem_degreename_language":"ja"},{"subitem_degreename":"Physical Science","subitem_degreename_language":"en"}]},"item_1617187136212":{"attribute_name":"Date Granted","attribute_value_mlt":[{"subitem_dategranted":"1998-03-25"}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"(1) Monomeric 10-Sb-5 Pentacoordinate Organoantimony Monohalides and Their Permutational Behavior. Kojima, S.; Takagi, R.; Nakata, H.; Yamamoto, Y.; Akiba, K.-y. Chem. Lett., 1995, 857-858."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(2) Asymmetric Darzens Condensation of Ketones with a-Chloroacetates by Means of (-)-8-Phenylmenthyl Auxiliary. Ohkata, K; Kimura. J.; Shinohara, Y.; Takagi, R.; Hiraga, Y. Chem. Commun., 1996, 2411-2412."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"(3) Excellent Z-Selective Olefin Formation Using Pentacoordinate Spirophosphoranes and Aldehydes. Wittig Type Reaction via Hexacoordinate Intermediates. Kojima, S.; Takagi, R.; Akiba, K.-y. J. Am. Chem. Soc., 1997, 119, 5970-5971."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(4) Synthesis of Norsesterterpene rac- and ent-Rhopaloic Acid A. Takagi, R.; Sasaoka, A.; Kojima, S.; Ohkata, K. Chem. Commnun., 1997, 1887-1888."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(5) Stereoselectivity in the Formation of 2,5-Disubstituted Tetrahydropyrans by Intramolecular Hetero-Michael Addition. Takagi, R.; Sasaoka, A.; Kojima, S.; Ohkata, K. Heterocycles, 1997, 45, 2313-2316."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(6) Asymmetric Induction in Darzens Condensation by Means of (-)-8-Phenylmenthyl and (-)-Menthyl Auxiliaries. Takagi, R.; Kimura, J.; Shinohara, Y.; Ohba, Y.; Takezono, K. Hiraga, Y.; Kojima, S.; Ohkata, K. J. Chem. Soc., Perkin Trans. 1, 1998, 689-698."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(7) Stereoselective Synthesis of (+)-Rhopaloic Acid A and (-)-ent- and (±)-rac-Rhopaloic Acid A. Takagi, R.; Sasaoka, A.; Nishitani, H.; Kojima, S.; Hiraga, Y.:, Ohkata, K. J. Chem. Soc., Perkin Trans. 1, 1998, 925-934."}],"subitem_relation_type":"references"},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1246/cl.1995.857","subitem_relation_type_select":"DOI"}},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/CC9960002411","subitem_relation_type_select":"DOI"}},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1021/ja964122w","subitem_relation_type_select":"DOI"}},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/A704563H","subitem_relation_type_select":"DOI"}},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.3987/COM-97-7970","subitem_relation_type_select":"DOI"}},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/A707310K","subitem_relation_type_select":"DOI"}},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1039/A707204J","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"diss_ko1768.pdf","filesize":[{"value":"84.2 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2006092/files/diss_ko1768.pdf"},"version_id":"c4fd4dcf-6ce3-4922-91fc-cf35eba349fc"}]},"item_1617944105607":{"attribute_name":"Degree Grantor","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"ja","subitem_degreegrantor_name":"広島大学"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"15401","subitem_degreegrantor_identifier_scheme":"kakenhi"}]},{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"en","subitem_degreegrantor_name":"Hiroshima University"}]}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"33814"},"item_title":"Asymmetric Induction in the Synthesis of Oxygen-Heterocyclic Compounds by Chiral Auxiliaries","item_type_id":"40003","owner":"41","path":["1730444916333"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2006092","relation_version_is_last":true,"title":["Asymmetric Induction in the Synthesis of Oxygen-Heterocyclic Compounds by Chiral Auxiliaries"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T02:48:26.583090+00:00"}