{"created":"2025-02-21T02:39:55.496806+00:00","id":2006061,"links":{},"metadata":{"_buckets":{"deposit":"b25c2546-225c-4ed2-98eb-c6e2a88296c8"},"_deposit":{"created_by":41,"id":"2006061","owner":"41","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2006061"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02006061","sets":["1730444908512:1730444916333"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Stereochemistry and Reactions of Pentacoordinate Organophosphorus Compounds with Martin Ligands","subitem_title_language":"en"},{"subitem_title":"マーチンリガンドを有する5配位有機リン化合物の立体化学と反応","subitem_title_language":"ja"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"梶山, 和政","creatorNameLang":"ja"},{"creatorName":"Kajiyama, Kazumasa","creatorNameLang":"en"}],"familyNames":[{"familyName":"梶山","familyNameLang":"ja"},{"familyName":"Kajiyama","familyNameLang":"en"}],"givenNames":[{"givenName":"和政","givenNameLang":"ja"},{"givenName":"Kazumasa","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright(c) by Author"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Contents  Chapter 1.General Introduction  　A.General Introduction / p1  　B.References / p12  Chapter 2.Syntheses and Characterization of Intra- and Intermolecular Hydrogen Bonding Isomers of P-H(Apical) Phosphoranes Bearing a Hydroxy Group.  　A.Introduction / p16  　B.Results and Discussion / p18  　C.Experimental Section / p38  　D.References / p55  Chapter 3.First Characterization of 10-P-5 Spirophosphoranes with an Apical Carbon-Equatorial Oxygen ring. Kinetic Studies on Pseudorotation.  　A.Introduction / p57  　B.Results and Discussion / p60  　C.Experimental Section / p75  　D.References / p99  Chapter 4.Kinetic Studies of Thermal Cyclization Reactions of P-H(apical) Phosphoranes Bearing a Hydroxy Group.  　A.Introduction / p101  　B.Results and Discussion / p104  　C.Experimental Section / p115  　D.References / p136  Acknowledgements / p138  List of Publications / p139","subitem_description_type":"TableOfContents"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186819068":{"attribute_name":"Identifier Registration","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.11501/3131312","subitem_identifier_reg_type":"JaLC"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"1"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicPageStart":"1"}]},"item_1617187087799":{"attribute_name":"Dissertation Number","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第1583号"}]},"item_1617187112279":{"attribute_name":"Degree Name","attribute_value_mlt":[{"subitem_degreename":"博士(理学)","subitem_degreename_language":"ja"},{"subitem_degreename":"Physical Science","subitem_degreename_language":"en"}]},"item_1617187136212":{"attribute_name":"Date Granted","attribute_value_mlt":[{"subitem_dategranted":"1997-03-25"}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"*(4) Synthesis and Characterization of Intra- and Intermolecular Hydrogen Bonding Isomers of P-H (apical) Phosphoranes Bearing a Hydroxyl Group and Their Thermal Cyclization. Kajiyama, K.; Kojima, S.; Akiba, K.-y. Tetrahedron Lett. 1996, 37, 8409-8412."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(5) First Characterization of a 10-P-5 Spirophosphorane with an Apical Carbon-Equatorial Oxygen Ring. Kinetic Studies on Pseudorotation of Stereoisomers. Kojima, S.; Kajiyama, K.; Nakamoto, M.; Akiba, K.-y. J. A in. Chem. Soc. 1996, 118, 12866-12867."}],"subitem_relation_type":"references"},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1016/0040-4039(96)01923-5","subitem_relation_type_select":"DOI"}},{"subitem_relation_type":"references","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1021/ja9621408","subitem_relation_type_select":"DOI"}}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-03-18"}],"displaytype":"simple","filename":"diss_ko1583.pdf","filesize":[{"value":"58.6 MB"}],"mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://hiroshima.repo.nii.ac.jp/record/2006061/files/diss_ko1583.pdf"},"version_id":"3ec952af-2ec9-457e-843f-586efdd7914a"}]},"item_1617944105607":{"attribute_name":"Degree Grantor","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"ja","subitem_degreegrantor_name":"広島大学"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"15401","subitem_degreegrantor_identifier_scheme":"kakenhi"}]},{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"en","subitem_degreegrantor_name":"Hiroshima University"}]}]},"item_1732771732025":{"attribute_name":"旧ID","attribute_value":"31888"},"item_title":"Stereochemistry and Reactions of Pentacoordinate Organophosphorus Compounds with Martin Ligands","item_type_id":"40003","owner":"41","path":["1730444916333"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-03-18"},"publish_date":"2023-03-18","publish_status":"0","recid":"2006061","relation_version_is_last":true,"title":["Stereochemistry and Reactions of Pentacoordinate Organophosphorus Compounds with Martin Ligands"],"weko_creator_id":"41","weko_shared_id":-1},"updated":"2025-02-21T02:40:11.184031+00:00"}