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ランタノイド反応剤の合成と選択的有機合成反応への利用に関する研究
https://doi.org/10.11501/3119852
https://doi.org/10.11501/3119852f3bd973c-98c9-43b3-8c9a-0255774eadb7
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
diss_ko1521.pdf (150.4 MB)
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| Item type | デフォルトアイテムタイプ_（フル）(1) | |||||||||
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| 公開日 | 2023-03-18 | |||||||||
| タイトル | ||||||||||
| タイトル | STUDIES ON THE LANTHANOID REAGENTS AND THEIR USE IN SELECTIVE ORGANIC SYNTHESES | |||||||||
| 言語 | en | |||||||||
| タイトル | ||||||||||
| タイトル | ランタノイド反応剤の合成と選択的有機合成反応への利用に関する研究 | |||||||||
| 言語 | ja | |||||||||
| 作成者 |
牧岡, 良和
× 牧岡, 良和
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| アクセス権 | ||||||||||
| アクセス権 | open access | |||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||
| 権利情報 | ||||||||||
| 権利情報 | Copyright(c) by Author | |||||||||
| 主題 | ||||||||||
| 主題Scheme | NDC | |||||||||
| 主題 | 430 | |||||||||
| 内容記述 | ||||||||||
| 内容記述タイプ | TableOfContents | |||||||||
| 内容記述 | Contents Chapter 1. Introduction / p1 Chapter 2. Applications of Lanthanoid Reductants to Organic Synthesis / p19 2. 1. Lanthanoid Mediated Intramolecular Cyclization of α, β-Unsaturated Carbonyl Compounds / p19 2. 2. Reduction of Heterocumulenes Promoted by Low-Valent Lanthanoids / p33 2. 3. Yb-TMSBr Promoted Homocoupling Reactions of Aliphatic Ketones, α, β-Unsaturated Ketones, and Imines / p49 2. 4. Synthesis of 1, 2-Diarylacetylenes and α-Silylalcohols from Acylsilanes Mediated by Ytterbium Metal / p69 2. 5. Deoxygenative Acylation of Diaryl Ketones with Acylsilanes Mediated by Lanthanoid Metals / p83 2. 6. A Facile Generation of Organosamarium η³-Allyl Complexes by Reductive Cleavage of Allylic Ethers with (C₅Me₅)₂Sm(thf)n / p93 2. 7. Generation of Allenic Samarium Complexes from Propargylic Ethers and (C₅Me₅)₂Sm(thf)₂ and Their Electrophilic Trapping / p117 Chapter 3. Synthetic Utilization of Lanthanoids as Lewis Acid Catalysts / p137 3. 1. Lanthanoid(II) or-(III) Alkoxide-Promoted Reactions of Silyl Ketene Acetals with Aldehydes / p137 3. 2. Facile Isomerization of Trialkylsilyl Enolates Catalyzed by Lanthanoid Trifluoromethanesulfonates / p159 3. 3. Ytterbium(III) Triflate Catalyzed Synthesis of Quinoline Derivatives from N-Arylaldimines and Vinyl Ethers / p197 Chapter 4. Lanthanoid-Diaryl Ketone or -Triaryl Imine Complexes in Organic Synthesis / p217 4. 1. Reaction of Lanthanoid Metals with Diaryl Thioketones / p217 4. 2. Reactions of Lanthanoid-Diaryl Ketone and -Thioketone Complexes with Isocyanides / p237 4. 3. Reaction of Lanthanoid-Diaryl Ketone Complexes with Alkynes / p253 4. 4. Selective Isomerization of Terminal Alkynes Catalyzed by Lanthanoid-Triaryl Imine Complexes / p267 4. 5. Isolation and Characterization of Ytterbium-Triaryl Imine Complexes / p289 4. 6. Reaction of Ytterbium-Triaryl Imine Complexes / p303 Chapter 5. Conclusions / p317 Publications and Presentations / p323 | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_db06 | |||||||||
| 資源タイプ | doctoral thesis | |||||||||
| 出版タイプ | ||||||||||
| 出版タイプ | NA | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_be7fb7dd8ff6fe43 | |||||||||
| ID登録 | ||||||||||
| ID登録 | 10.11501/3119852 | |||||||||
| ID登録タイプ | JaLC | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 1. "Reduction of Heterocumulenes Promoted by Low-valent Lanthanoids" Yoshikazu Makioka Yun-Shan Liu, Bei-Zhi Bei, Zhi-Hua Zhou, Taka-aki Shindo, Yuki Taniguchi, Ken Takaki, and Yuzo Fujiwara, Nippon Kagaku Kaishi, 475-481 (1993). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 2. "Lanthanoid(II) or -(III) Alkoxide-Promoted Reactions of Silyl Ketene Acetals with Aldehydes" Yoshikazu Makioka, Ikuko Nakagawa, Yuki Taniguchi, Ken Takaki, and Yuzo Fujiwara, J. Org. Chem., 58, 4771-4774 (1993). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 3. "Novel Synthesis of 1, 2-Diarylacetylenes and α-Silylalcohols from Acylsilanes Mediated by Ytterbium Metal" Yuki Taniguchi, Nobuto Fujii, Shin-ya Uebori, Yoshikazu Makioka, Ken Takaki, and Yuzo Fujiwara, Chem. Lett., 1165-1168 (1993). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 4. "Lanthanoid Mediated Intramolecular Cyclization of α, β-Unsaturated Carbonyl Compounds" Yuki Taniguchi, Takeshi Kusudo, Fumikazu Beppu, Yoshikazu Makioka, Ken Takaki, and Yuzo Fujiwara, Nippon Kagaku Kaishi, 62-67 (1994). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 5. "Ytterbium Metal Mediated Desulfurization and Coupling Reaction of Diaryl Thioketones" Yoshikazu Makioka, Shin-ya Uebori, Masumi Tsuno, Yuki Taniguchi, Ken Takaki, and Yuzo Fujiwara, Chem. Lett., 611-614 (1994). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 6. "Facile Isomerization of Trimethylsilyl Ketene Acetals to α-Trimethylsilyl Esters Catalyzed by Lanthanoid Trifluoromethanesulfonates" Yoshikazu Makioka, Yuki Taniguchi, Ken Takaki, and Yuzo Fujiwara, Chem. Lett., 645-648 (1994). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 7. "Yb-TMSBr Promoted Homocoupling Reactions of Aliphatic Ketones and α, β-Unsaturated Ketones" Yuki Taniguchi, Manabu Nakahashi, Tatsuhiro Kuno, Masumi Tsuno, Yoshikazu Makioka, Ken Takaki, and Yuzo Fujiwara, Tetrahedron Lett., 35, 4111-4114 (1994). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 8. "Novel Deoxygenative Acylation of Diaryl Ketones with Acylsilanes Mediated by Lanthanoid Metal" Yuki Taniguchi, Akihiro Nagafuji, Yoshikazu Makioka, Ken Takaki, and Yuzo Fujiwara, Tetrahedron Lett., 35, 6897-6898 (1994). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 9. "A Facile Generation of Organosamarium η3-Allyl Complexes by Reductive Cleavage of Allylic Ethers with (C5Me5)2Sm(THF)n" Ken Takaki, Takeshi Kusudo, Shinya Uebori, Yoshikazu Makioka, Yuki Taniguchi, and Yuzo Fujiwara, Tetrahedron Lett., 36, 1505-1508 (1995). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 10. "Ytterbium(III) Triflate Catalyzed Synthesis of Quinoline Derivatives from N-Arylaldimines and Vinyl Ethers" Yoshikazu Makioka, Takaaki Shindo, Yuki Taniguchi, Ken Takaki, and Yuzo Fujiwara, Synthesis, 801-804 (1995). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 11. "Generation of Allenic Samarium Complexes from Propargylic Ethers and (C5Me5)2Sm(thf)2, and Their Electrophilic Trapping" Yoshikazu Makioka, Koji Koyama, Tetsushi Nishiyama, Ken Takaki, Yuki Taniguchi, and Yuzo Fujiwara, Tetrahedron Lett., 36, 6283-6286 (1995). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 12. "Lanthanoid Metal Promoted Reaction of Diaryl Ketones and Thioketones with Isocyanides" Yoshikazu Makioka, Masumi Tsuno, Ken Takaki, Yuki Taniguchi, and Yuzo Fujiwara, Chem. Lett., 821-822 (1995). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 関連名称 | 13. "Synthetic Utility of Umpoled Diaryl Thioketone-Lanthanoid Intermediates: Desulfurization, Cross Coupling with Electrophiles, and Desulfurizative Homocoupling" Yoshikazu Makioka, Masumi Tsuno, Shin-ya Uebori, Yuki Taniguchi, Ken Takaki, and Yuzo Fujiwara, J. Org. Chem., 61, 372-375 (1996). | |||||||||
| 関連情報 | ||||||||||
| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1246/nikkashi.1993.475 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1021/jo00069a055 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1246/cl.1993.1165 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1246/nikkashi.1994.62 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1246/cl.1994.611 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1246/cl.1994.645 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1016/S0040-4039(00)73126-1 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1016/0040-4039(94)85035-6 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1016/0040-4039(95)00071-J | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1055/s-1995-4002 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1016/0040-4039(95)01260-O | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1246/cl.1995.821 | |||||||||
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| 関連タイプ | references | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | http://dx.doi.org/10.1021/jo951355h | |||||||||
| 開始ページ | ||||||||||
| 開始ページ | 1 | |||||||||
| 書誌情報 |
p. 1 |
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| 学位授与番号 | ||||||||||
| 学位授与番号 | 甲第1521号 | |||||||||
| 学位名 | ||||||||||
| 言語 | ja | |||||||||
| 学位名 | 博士(工学) | |||||||||
| 学位名 | ||||||||||
| 言語 | en | |||||||||
| 学位名 | Engineering | |||||||||
| 学位授与年月日 | ||||||||||
| 学位授与年月日 | 1996-03-26 | |||||||||
| 学位授与機関 | ||||||||||
| 学位授与機関識別子Scheme | kakenhi | |||||||||
| 学位授与機関識別子 | 15401 | |||||||||
| 言語 | ja | |||||||||
| 学位授与機関名 | 広島大学 | |||||||||
| 学位授与機関 | ||||||||||
| 言語 | en | |||||||||
| 学位授与機関名 | Hiroshima University | |||||||||
| 旧ID | 31869 | |||||||||
