{"created":"2025-02-21T02:05:20.030271+00:00","id":2005989,"links":{},"metadata":{"_buckets":{"deposit":"e774d44b-7a67-4d46-aa47-06cebdbcadf4"},"_deposit":{"created_by":41,"id":"2005989","owner":"41","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2005989"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02005989","sets":["1730444908512:1730444916333"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Stereochmistry of Tetra- and Pentacoordinate Organic Compounds of Phosphorus and Antimony","subitem_title_language":"en"},{"subitem_title":"4配位および5配位有機リンおよびアンチモン化合物の立体化学","subitem_title_language":"ja"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"小島, 聡志","creatorNameLang":"ja"},{"creatorName":"Kojima, Satoshi","creatorNameLang":"en"}],"familyNames":[{"familyName":"小島","familyNameLang":"ja"},{"familyName":"Kojima","familyNameLang":"en"}],"givenNames":[{"givenName":"聡志","givenNameLang":"ja"},{"givenName":"Satoshi","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright(c) by Author"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"Contents  General Introduction / p1  References / p18  Chapter1.Preparation of Optically Active Phosphine Oxides via Wittig Type Rearrangement and Phosphine Sulfides via Alkylation of Lithium Phosphinothioites.  　1.Introduction / p21  　2.Results and Discussion / p25  　3.Experimental / p50  　4.References / p70  Chapter2.Characterization of the FirstEnantiomericPairs of Stereochemically Definable Hypervalent 10-P-5 Phosphoranes with Asymmetry Only at Phosphorus.  　1.Introduction / p72  　2.Results and Discussion / p74  　3.Experimental / p97  　4.References / p108  Chapter3.The First Stereochemical Characterization of Configurationally Stable Diastereomers of Hypervalent 10-Sb-5 Stiboranes and Acceleration of Intramolecular Permutation by Donor Solvents  　1.Introduction / p110  　2.Results and Discussion / p112  　3.Experimental / p137  　4.References / p142  List of Publications / p145","subitem_description_type":"TableOfContents"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_1617186819068":{"attribute_name":"Identifier Registration","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.11501/3106021","subitem_identifier_reg_type":"JaLC"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"1"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicPageStart":"1"}]},"item_1617187087799":{"attribute_name":"Dissertation Number","attribute_value_mlt":[{"subitem_dissertationnumber":"乙第2677号"}]},"item_1617187112279":{"attribute_name":"Degree Name","attribute_value_mlt":[{"subitem_degreename":"博士(理学)","subitem_degreename_language":"ja"},{"subitem_degreename":"Physical Science","subitem_degreename_language":"en"}]},"item_1617187136212":{"attribute_name":"Date Granted","attribute_value_mlt":[{"subitem_dategranted":"1995-03-07"}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"*(1) The Wittig Rearrangement of Chiral Phosphinothioates Induced by the Tin-Lithium Transmetallation. Kawashima, T.; Kojima, S.; Miyake, T.; Inamoto, N. Tetrahedron Lett. 1989, 201-204."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(2) The Optically Active Phosphinodithioates. Synthesis and Conversion to Optically Active Phosphine Sulfides. Kawashima, T.; Kojima, S.; Inamoto, N. Chem. Lett. 1989, 849-852."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(3) Synthesis, Structure, and Reactions of a 10-Sb-4 Type Antimony Ate Complex. Akiba, K.-y.; Nakata, H.; Yamamoto, Y.; Kojima, S. Chem. Lett. 1992, 1559-1562."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"(4) Synthesis, Structure, and Reactions of 10-Sn-5 Organotin Ate Complexes. Akiba, K.-y. ; Ito, Y.; Kondo, F.; Ohashi, N.; Sakaguchi, A.; Kojima, S.; Yamamoto, Y. Chem. Lett. 1992, 1562-1566."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"(5) 121Sb Mossbauer Spectra of Hexafluorocumyl Alcohol Complexes of Sb(V) and of Sb(III) with Negative Quadrupole Coupling Constants. Takeda, M.; Takahashi, M.; Yanagida, Y.; Kojima, S.; Akiba, K.-y. Chem. Lett. 1993, 2037-2040."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"(6) 121Sb and 127I Mossbauer Spectroscopic Study on Sb-I Hypervalent Bonds in Trigonal Bipyramidal Antimony (V) Complexes. Takeda, M.; Takahashi, M.; Yanagida, Y.; Kojima, S.; Akiba, K.-y.; Ito, Y. Hyperfine Interactions 1994, 84, 439-446."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(7) The Wittig Rearrangement of Chiral S-Methyl Phosphinothioates Promoted by Direct Deprotonation with Lithium Dialkylamides. Kawashima, T.; Kojima, S.; Inamoto, N Bull. Chem. Soc. Jpn. 1994, 67, 2603-2606."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"*(8) Characterization of an Optically Active Pentacoordinate Phosphorane with Asymmetry Only at Phosphorus. Kojima, S.; Kajiyama, K.; Akiba, K.-y. 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