{"created":"2025-02-21T02:02:06.018804+00:00","id":2005966,"links":{},"metadata":{"_buckets":{"deposit":"ba75127f-321d-443a-a964-9e62b27bc776"},"_deposit":{"created_by":41,"id":"2005966","owner":"41","owners":[41],"pid":{"revision_id":0,"type":"depid","value":"2005966"},"status":"published"},"_oai":{"id":"oai:hiroshima.repo.nii.ac.jp:02005966","sets":["1730444908512:1730444916333"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"シラシクロアルカンおよび関連カチオンラジカルの電子スピン共鳴分光法による研究 : 電子構造,分子運動および反応性","subitem_title_language":"ja"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"駒口, 健治","creatorNameLang":"ja"},{"creatorName":"Komaguchi, Kenji","creatorNameLang":"en"}],"familyNames":[{"familyName":"駒口","familyNameLang":"ja"},{"familyName":"Komaguchi","familyNameLang":"en"}],"givenNames":[{"givenName":"健治","givenNameLang":"ja"},{"givenName":"Kenji","givenNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186499011":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"Copyright(c) by Author"}]},"item_1617186609386":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"540","subitem_subject_scheme":"NDC"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"目次 / p1  第I章 序論 / p1  　1.1.緒言 / p1  　1.2.基本的有機カチオンラジカルの電子構造 / p3  　1.3.本研究の目的と概要 / p7  　参考文献 / p10  第II章 マトリックス単離法と電子スピン共鳴法 / p13  　2.1.マトリックス単離法 / p13  　2.2.電子スピン共鳴(ESR)法 / p18  　2.3.ESRスペクトルの超微細構造の解析 / p23  　参考文献 / p25  第III章 シラシクロヘキサン(cSiC5)系カチオンラジカル / p27  　3.1.緒言 / p27  　3.2.実験 / p28  　3.3.結果と考察 / p28  　3.4.まとめ / p76  　参考文献 / p77  第IV章 シラシクロペンタン(cSiC4)系カチオンラジカル / p79  　4.1.緒言 / p79  　4.2.実験 / p80  　4.3.結果と考察 / p80  　4.4.まとめ / p96  　参考文献 / p97  第V章 シラシクロブタン(cSiC3)系カチオンラジカル / p98  　5.1.緒言 / p98  　5.2.実験 / p99  　5.3.結果と考察 / p100  　5.4.まとめ / p128  　参考文献 / p129  第VI章 シクロペンタンメチル誘導体カチオンラジカル / p130  　6.1.緒言 / p130  　6.2.実験 / p131  　6.3.結果と考察 / p132  　6.4.まとめ / p155  　参考文献 / p157  第VII章 総括 / p158  謝辞 / p163  付録 / p164  　A.溶質の合成方法 / p164  　　1.cSiC5系 / p164  　　2.cSiC4系 / p167  　　3.cSiC3系 / p168  　　4.Me-d3-cC5 / p168  　　参考文献 / p170  　B.発表論文リスト / p171  　　1.本論文関連 / p171  　　2.その他 / p172","subitem_description_type":"TableOfContents"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_1617186819068":{"attribute_name":"Identifier Registration","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.11501/3079821","subitem_identifier_reg_type":"JaLC"}]},"item_1617187024783":{"attribute_name":"Page Start","attribute_value_mlt":[{"subitem_start_page":"1"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicPageStart":"1"}]},"item_1617187087799":{"attribute_name":"Dissertation Number","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第1205号"}]},"item_1617187112279":{"attribute_name":"Degree Name","attribute_value_mlt":[{"subitem_degreename":"博士(工学)","subitem_degreename_language":"ja"},{"subitem_degreename":"Engineering","subitem_degreename_language":"en"}]},"item_1617187136212":{"attribute_name":"Date Granted","attribute_value_mlt":[{"subitem_dategranted":"1994-03-16"}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_1617353299429":{"attribute_name":"Relation","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"(1) \"An Asymmetrically Distorted Structure of the 1-Methylsilacyclohexane Radical Cation: ESR Evidence\", M. Shiotani, K. Komaguchi, J. Ohshita, and M. Ishikawa, Chem. Phys. Lett."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"1992, 188(1, 2), pp. 93-99."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"(2) \"Structure and Ring Puckering Motion of the σ-localized Silacyclobutane Radical Cation: ESR Evidence\", K. Komaguchi, M. Shiotani, M. Ishikawa, and K. Sasaki, Chem. Phys. Lett."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"1992, 200(6), pp. 580-586."}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"(3) \"Upon the Structure of cC5H10+ : Asymmetrical SOMO of Methylsubstituted Cyclopentane Cation Radicals\", M. Lindgren, K. Komaguchi, M. Shiotani, and K. Sasaki, J. Phys. Chem. 投稿中"}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"(4) \"Reversible Thermal and Photoinduced Rearrangement between the Symmetric and Asymmetric Silacyclobutane Radical Cations\", K. Komaguchi, M. Shiotani, and M. Ishikawa, Chem. Phys. Lett. 投稿予定"}],"subitem_relation_type":"references"},{"subitem_relation_name":[{"subitem_relation_name_text":"(5) \"Asymmetrically Distorted Structure, Selective Bond Length Alternation and Reactions of some Silacycloalkane Radical Cations : An ESR Study\", K. Komaguchi, M. Shiotani, and M. Ishikawa, J. Phys. 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